研究员
郑超
职  称: 研究员
学  历: 研究生
电  话: 021-54925336
职  务:
传  真:
电子邮件: zhengchao@sioc.ac.cn
个人网页:
通信地址: 上海市零陵路345号
个人简历

2007-2012 中国科学院上海有机化学研究所博士。导师:游书力研究员和李玉学研究员

2003-2007 上海交通大学化学化工学院学士。导师:舒谋海教授

 

研究方向

物理有机化学、手性合成

社会任职
获奖及荣誉

上海市自然科学奖一等奖(排名第三,2016年)

国家自然科学奖二等奖(排名第三,2017年)

中国科学院青年创新促进会会员(2017年)

上海市青年科技启明星(2018年)

上海市青年拔尖人才(2020年)

中国科学院青年创新促进会优秀会员(2021年)

代表论著

1. Zheng, Y.; Zhang, W.-Y.; Gu, Q.; Zheng, C.*; You, S.-L.* Cobalt(III)-Catalyzed Asymmetric Ring-Opening of 7-Oxabenzonorbornadienes via Indole C–H Functionalization. Nat. Commun.2023, 14, 1094.

2. Liu, C.-X.; Xie, P.-P.; Zhao, F.; Wang, Q.; Feng, Z.; Wang, H.; Zheng, C.*; You, S.-L.* Explicit Mechanism of Rh(I)-Catalyzed Asymmetric C–H Arylation and Facile Synthesis of Planar Chiral Ferrocenophanes. J. Am. Chem. Soc.2023, 145, 4765-4773.

3. Zhang, W.-W.; Wang, Q.; Zhang, S.-Z.; Zheng, C.*; You, S.-L.* Rh-Catalyzed Asymmetric Satoh–Miura-type Reactions for Building-up Axial Chirality: Counteranion Directed Switch of Reaction Pathways. Angew. Chem. Int. Ed.2023, 62, e202214460.

4. Jiang, R.; Zhao, Q.-R.; Zheng, C.*; You, S.-L.* Structurally Defined anti-π-Allyliridium Complexes Catalyze Z-Retentive Asymmetric Allylic Alkylation of Oxindoles. Nat. Catal.2022, 5, 1089-1097.

5. Zhu, M.; Zhang, X.*; Zheng, C.*; You, S.-L.* Energy-Transfer-Enabled Dearomative Cycloaddition Reactions of Indoles/Pyrroles via Excited-State Aromatics. Acc. Chem. Res.2022, 55, 2510-2525.

6. Liu, Y.-Z.; Song, H.; Zheng, C.*; You, S.-L.* Cascade Asymmetric Dearomative Cyclization Reactions via Transition-metal-catalysis. Nat. Synth.2022, 1, 203-216.

7. Wang, Q.; Nie, Y.-H.; Liu, C.-X.; Zheng, W.-W.; Wu, Z.-J.; Gu, Q.; Zheng, C.*; You, S.-L.* Rhodium(III)-Catalyzed Enantioselective C–H Activation/Annulation of Ferrocenecarboxamides with Internal Alkynes. ACS Catal.2022, 12, 3083-3093.

8. Zhu, M.; Zheng, C.* post-Spin Crossing Dynamics Determines the Regioselectivity in Open-shell Singlet Biradical Recombination. Org. Chem. Front.2022, 9, 995-1003.

9. Zhu, M.; Huang, X.-L.; Sun, S.; Zheng, C.*; You, S.-L.* Visible-Light-Induced Dearomatization of Indoles/Pyrroles with Vinylcyclopropanes: Expedient Synthesis of Structurally Diverse Polycyclic Indolines/Pyrrolines. J. Am. Chem. Soc.2021, 143, 13441-13449.

10. Huang, L.; Xie, J.-H.; Cai, Y.; Zheng, C.*; Hou, X.-L.; Dai, L.-X.; You, S.-L.* Enantioselective Synthesis of Polycyclic Pyrrole Derivatives by Iridium-Catalyzed Asymmetric Allylic Dearomatization and Ring-expansive Migration Reactions. Chem. Commun.2021, 57, 5390-5393.

11. Zheng, C.; You, S.-L.* Advances in Catalytic Asymmetric Dearomatization. ACS Cent. Sci.2021, 7, 432-444.

12. Jiang, R.; Ding, L.; Zheng, C.; You, S.-L.* Iridium-Catalyzed Z-Retentive Asymmetric Allylic Substitution Reactions. Science2021, 371, 380-386.

13. Zhu, M.; Xu, H.; Zhang, X.*; Zheng, C.*; You, S.-L.* Visible-light-induced Intramolecular Double Dearomative Cycloaddition of Arenes. Angew. Chem. Int. Ed.2021, 60, 7036-7040.

14. Liu, Q.-Q.; Zheng, C.*; You, S.-L.* Silica Gel-promoted Synthesis of Multisubstituted Spiroindolenines from Tryptamines and γ-Chloro-α,β-Unsaturated Ketones. Tetrahedron2021, 77, 131765.

15. Zhu, M.; Zhang, X.*; Zheng, C.*; You, S.-L.* Visible-light-induced Dearomatization via [2+2] Cycloaddition or 1,5-Hydrogen Atom Transfer: Divergent Reaction Pathways of Transient Diradicals. ACS Catal.2020, 10, 12618-12626.

16. Zheng, C.* Divergent Pathways and Dynamics Effects of Intramolecular Hydride Transfer Reactions Mediated by Cp*M(III) Complexes (M = Co, Rh, Ir). Chin. J. Chem.2020, 38, 1579-1584.

17. Zhu, M.; Huang, X.-L.; Xu, H.; Zhang, X.*; Zheng, C.*; You, S.-L.* Visible-Light-Mediated Synthesis of Cyclobutene-Fused Indolizidines and Related Structural Analogs. CCS Chem.2020, 2, 652-664.

18. Zheng, C.*; You, S.-L.* Exploring the Chemistry of Spiroindolenines by Mechanistically-Driven Reaction Development: Asymmetric Pictet–Spengler-type Reactions and Beyond. Acc. Chem. Res.2020, 53, 974-987.

19. Rossi-Ashton, J. A.; Clarke, A. K.; Donald, J. R.; Zheng, C.*; Taylor, R. J. K.*; Unsworth, W. P.*; You, S.-L.* Iridium Catalyzed Enantioselective Intermolecular Indole C2-Allylation. Angew. Chem., Int. Ed.2020, 59, 7598-7604.

20. Yang, P.#; Xu, R.-Q.#; Zheng, C.*; You, S.-L.* Pd-catalyzed Dearomatization of Indole Derivatives via Intermolecular Heck Reactions. Chin. J. Chem.2020, 38, 235-241.

21. Xia, Z.-L.; Xu-Xu, Q.-F.; Zheng, C.*; You, S.-L.* Chiral Phosphoric Acid-Catalyzed Asymmetric Dearomatization Reactions. Chem. Soc. Rev.2020, 49, 286-300.

22. Zheng, C.*; You, S.-L.* Catalytic Asymmetric Dearomatization Reaction Enabled Total Synthesis of Indole-based Natural Products. Nat. Prod. Rep.2019, 36, 1589-1605.

23. Zhu, M.; Zheng, C.*; Zhang, X.*; You, S.-L.* Synthesis of Cyclobutane-Fused Angular Tetracyclic Spiroindolines via Visible-Light-Promoted Intramolecular Dearomatization of Indole Derivatives. J. Am. Chem. Soc.2019, 141, 2636-2644.

24. Xia, Z.-L.; Zheng, C.*; Liang, X.-W.; Cai, Y.; You, S.-L.* Manipulation of Spiroindolenine Intermediates for Enantioselective Synthesis of 3-(Indol-3-yl)-pyrrolidines. Angew. Chem., Int. Ed.2019, 58, 1158-1162.

25. Yang, Z.-P.; Jiang, R.; Wu, Q.-F.; Huang, L.; Zheng, C.*; You, S.-L.* Iridium-Catalyzed Intramolecular Asymmetric Allylic Dearomatization of Benzene Derivatives. Angew. Chem., Int. Ed.2018, 57, 16190-16193.

26. Zheng, C.*; Xia, Z.-L.; You, S.-L.* Unified Mechanistic Understandings of Pictet–Spengler Reactions. Chem2018, 4, 1952-1966.

27. Yang, Z.-P.; Jiang, R.; Zheng, C.*; You, S.-L.* Iridium-Catalyzed Intramolecular Asymmetric Allylic Alkylation of Hydroxyquinolines: Simultaneous Weakening of the Aromaticity of Two Consecutive Aromatic Rings. J. Am. Chem. Soc.2018, 140, 3114-3119.

28. Xia, Z.-L.; Zheng, C.*; Wang, S.-G.; You, S.-L.* Catalytic Asymmetric Dearomatization of Indolyl Dihydropyridines through an Enamine Isomerization/Spirocyclization/Transfer Hydrogenation Sequence.Angew. Chem., Int. Ed.2018, 57, 2653-2656.

29. Wang, Y.; Zheng, C.*; You, S.-L.* Iridium-Catalyzed Asymmetric Allylic Dearomatization by a Desymmetrization Strategy. Angew. Chem., Int. Ed.2017, 56, 15093-15097.

30. Zheng, C.; You, S.-L.* Catalytic Asymmetric Dearomatization by Transition-Metal-Catalysis: A Method for Transformations of Aromatic Compounds. Chem2016, 1, 830-857.

31. Wu, Q.-F.; Zheng, C.*; Zhuo, C.-X.; You, S.-L.* Highly Efficient Synthesis and Stereoselective Migration Reactions of Chiral Five-Membered Aza-Spiroindolenines: Scope and Mechanistic Understanding. Chem. Sci.2016, 7, 4453-4459.

32. Zheng, C.*; Zheng, J.; You, S.-L.* A DFT Study on Rh-Catalyzed Asymmetric Dearomatization of 2-Naphthols Initiated with C–H Activation: A Re?ned Reaction Mechanism and Origins of Multiple Selectivity. ACS Catal.2016, 6, 262-271.

33. Zheng, C.*; Zhuo, C.-X.; You, S.-L.* Mechanistic Insights into the Pd-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Multisubstituted Pyrroles: Understanding the Remarkable Regio- and Enantioselectivity. J. Am. Chem. Soc.2014, 136, 16251-16259.

34. Liu, H.; Zheng, C.*; You, S.-L.* Fe(OTf)3 Catalyzed Annulation of 2,3-Disubstituted Indoles with Aziridines. Chin. J. Chem.2014, 32, 709-714.

35. Liu, H.; Zheng, C.*; You, S.-L.* Catalytic C6 Functionalization of 2,3-Disubstituted Indoles by Scandium Triflate. J. Org. Chem.2014, 79, 1047-1054.

36. Zheng, C.; You, S.-L.* Recent Development of Direct Asymmetric Functionalization of Inert C–H Bonds. RSC Adv.2014, 4, 6173-6214.

37. Zheng, C.*; Wu, Q.-F.; You, S.-L.* A Combined Theoretical and Experimental Investigation into the Highly Stereoselective Migration of Spiroindolenines. J. Org. Chem.2013, 78, 4357-4365.

承担科研项目情况