研究员
高希珂
职  称: 研究员
学  历: 博士研究生
电  话: 021-54925072
职  务: 课题组长
传  真: 021-64166128
电子邮件: gaoxk@mail.sioc.ac.cn
通信地址: 上海市零陵路345号
个人简历

高希珂,中国科学院上海有机化学研究所研究员,课题组长,博士生导师,隶属于金属有机化学国家重点实验室。2008于中国科学院化学研究所获理学博士学位,同年进入上海有机所工作,从事有机功能材料化学研究,历任副研究员和研究员。入选上海市青年科技启明星计划和优秀学术带头人,获得优秀青年科学基金和国家杰出青年科学基金资助。

研究方向
  1. 非苯芳烃化学(薁化学)
  2. 有机光电功能材料
  3. 有机生物功能材料
社会任职
获奖及荣誉

上海市青年科技启明星计划(2011)

中国科学院卢嘉锡青年人才奖(2013)

中国科学院青年创新促进会首批优秀会员(2015)

中国科学院上海分院青年五四奖章(2015

优秀青年科学基金(2015)

上海市科技系统青年五四奖章(2016)

上海市优秀学术带头人(2019)

上海市自然科学奖二等奖(2020,第一完成人)

ThiemeChemistryJournalAward2021

国家杰出青年科学基金 (2022)

华为“难题揭榜”火花奖(2023)

代表论著

1. Junjun Xiang, Zhiwei Yang, Junrui Zhao, Chao Duan, Jingtao Wang,* and Xike Gao.* Poly(vinyl azulene)s: An Emerging Class of Poly(vinyl arene)s. Macromolecules2024, 57, 7516-7523.

2. Heqi Gao,# Yiming Yao,# Cong Li, Jingtian Zhang, Haoyun Yu, Xiaodi Yang, Jing Shen,Qian Liu, Ruitong Xu, Xike Gao,*and Dan Ding.*Fused Azulenyl Squaraine Derivatives Improve Phototheranostics inthe Second Near-Infrared Window by Concentrating Excited StateEnergy on Non-Radiative Decay Pathways. Angew. Chem. Int. Ed. 2024, 63, e202400372. (# Co-first authors)

3. Jiangao Li, Zhijun Zhang,* Shanshan Jiang, Miaomiao Kang, Deliang Wang, Xue Li,Peng Huang, Xike Gao,* Dong Wang,* and Ben Zhong Tang.*NIR-II Excitable Semiconducting Polymers with AIECharacteristics for Fluorescence-Photoacoustic Imaging-Guided SynergisticPhototherapy. Adv. Funct. Mater.2024, 34, 2401627.

4. Jiangao Li, Miaomiao Kang,* Zhijun Zhang, Xue Li, Weilin Xu, Dong Wang,* Xike Gao,* and Ben Zhong Tang.*Synchronously Manipulating Absorption and Extinction Coefficient of Semiconducting Polymers via Precise Dual-Acceptor Engineering for NIR-II Excited Photothermal Theranostics. Angew. Chem. Int. Ed. 2023, 62, e202301617.

5. Chengyang Zhang,# Jie Cheng,# Qingqing Wu,# Songjun Hou, Sai Feng, Bo Jiang, Colin J. Lambert,* Xike Gao,* Yueqi Li,* and Jinghong Li.*Enhanced π–π Stacking between Dipole-Bearing Single Molecules Revealed by Conductance Measurement. J. Am. Chem. Soc.2023, 145, 1617-1630.(# Co-first authors)

6. Yang Wang, Wen Liang Tan, Junjun Xiang, Congwu Ge, Christopher R. McNeill,* and Xike Gao.*Tuning Dipole Orientation of 2,6-Azulene Units in Conjugated Copolymers by C–H Activation Strategy toward High-Performance Organic Semiconductor. ACS Macro Lett. 2023, 12, 487-493.

7. Junjun Xiang, Doan Vu, Mengmeng He, Chao Duan, Congwu Ge, Christopher R. McNeill,*andXike Gao.*Poly(2,6-azulene vinylene)s: Azulene Orientation Control and Property Studies. Macromolecules2023, 56, 9475-9488.

8. Chao Duan, Jianwei Zhang, Junjun Xiang, Xiaodi Yang,*andXike Gao.* Azulene-Embedded [n]Helicenes (n = 5, 6 and 7).  Angew. Chem. Int. Ed. 2022, 61, e202201494.

9. Mingyao Li,#Huanyan Fu,#Boyu Wang,#Jie Cheng,#Weilin Hu, Bing Yin, Peizhen Peng, Shuyao Zhou, Xike Gao,* Chuancheng Jia,* and Xuefeng Guo.*Dipole-Modulated Charge Transport through PNP-Type Single-Molecule Junctions.J. Am. Chem. Soc.2022, 144, 20797-20803.(# Co-first authors)

10. Bin Hou, Zhuofan Zhou, Cui Yu, Xiao-Song Xue, Jianwei Zhang, Xiaodi Yang, Jing Li, Congwu Ge, Jingtao Wang,*andXike Gao.* 2,6-Azulene-based Homopolymers: Design, Synthesis, and Application in Proton Exchange Membrane Fuel Cells.ACS Macro Lett. 2022, 11, 680-686.

11. Junjun Xiang, Wen Liang Tan, Jianwei Zhang, Yang Wang, Chao Duan, Christopher R. McNeill, Xiaodi Yang, Congwu Ge,andXike Gao.*Poly(2,6-azuleneethynylene)s: Design, Synthesis and Property Studies. Macromolecules2022, 55, 8074-8083.

12. Yiming Yao, Yuan Zhang, Jianwei Zhang, Xiaodi Yang, Dan Ding, Yang Shi,* Huae Xu,* and Xike Gao.*Azulene-Containing Squaraines for Photoacoustic Imaging and Photothermal Therapy. ACS Appl. Mater. Interfaces 2022, 14, 19192-19203.

13. Bin Hou, Jing Li, Zhuofan Zhou, Wen Liang Tan, Xiaodi Yang, Jianwei Zhang, Christopher R. McNeill, Congwu Ge, Jingtao Wang,* and Xike Gao.*Incorporation of Electron-Rich Indacenodithiophene Units into the Backbone of 2,6-Azulene-Based Conjugated Polymers for Proton-Responsive Materials and p-Type Polymeric Semiconductors.ACS Materials Lett.2022, 4, 392-400.

14. Hanshen Xin, Bin Hou,andXike Gao.* Azulene-based π-functional materials: design, synthesis, and applications. Acc. Chem. Res.2021, 54, 1737-1753.

15. Hanshen Xin, Jing Li, Ru-Qiang Lu, Xike Gao,* and Timothy. M. Swager.* Azulene–Pyridine-Fused Heteroaromatics. J. Am. Chem. Soc.2020, 142, 13598-13605.

16. Honglei Gao,# Congwu Ge,# Bin Hou, Hanshen Xin,andXike Gao.* Incorporation of 1,3-Free-2,6-Connected Azulene Units into the Backbone of Conjugated Polymers: Improving Proton Responsiveness and Electrical Conductivity. ACS Macro Lett.2019, 8, 1360-1364. (# Co-first authors)

17. Hanshen Xin, Congwu Ge, Xuechen Jiao, Xiaodi Yang, Kira Rundel, Christopher R. McNeill, and Xike Gao.* Incorporation of 2,6-Connected Azulene Units into the Backbone of Conjugated Polymers: Towards High-Performance Organic Optoelectronic Materials. Angew. Chem. Int. Ed.2018, 57, 1322-1326.

18. Hanshen Xin, Congwu Ge, Xiaodi Yang, Honglei Gao, Xiaochun Yang, and Xike Gao.* Biazulene diimides: a new building block for organic electronic materials. Chem. Sci.2016, 7, 6701-6705.

19. Fengjiao Zhang,# Yunbin Hu,# Torben, Schuettfort, Chong-an Di,* Xike Gao,* Christopher R McNeill,* Lars Thomsen, Stefan C B Mannsfeld, Wei Yuan, Henning Sirringhaus, and Daoben Zhu.* Critical Role of Alkyl Chain Branching of Organic Semiconductors in Enabling Solution-Processed N-channel Organic Thin-film Transistors with Mobility of up to 3.50 cm2V-1s-1. J. Am. Chem. Soc.2013, 135, 2338-2349. (# Co-first authors)

20. Xike Gao,* Chong-an Di,* Yunbin Hu, Xiaodi Yang, Hongyu Fan, Feng Zhang, Yunqi Liu, Hongxiang Li, and Daoben Zhu. Core-expanded naphthalene diimides fused with 2-(1,3-dithiol-2-ylidene)malonitrile groups for high-performance, ambient-stable, solution-processed n-channel organic thin film transistors. J. Am. Chem. Soc.2010, 132, 3697-3699.

承担科研项目情况