高希珂,中国科学院上海有机化学研究所研究员,课题组长,博士生导师,隶属于金属有机化学国家重点实验室。2008于中国科学院化学研究所获理学博士学位,同年进入上海有机所工作,从事有机功能材料化学研究,历任副研究员和研究员。入选上海市青年科技启明星计划和优秀学术带头人,获得优秀青年科学基金和国家杰出青年科学基金资助。
上海市青年科技启明星计划(2011)
中国科学院卢嘉锡青年人才奖(2013)
中国科学院青年创新促进会首批优秀会员(2015)
中国科学院上海分院青年五四奖章(2015)
优秀青年科学基金(2015)
上海市科技系统青年五四奖章(2016)
上海市优秀学术带头人(2019)
上海市自然科学奖二等奖(2020,第一完成人)
Thieme Chemistry Journal Award (2021)
国家杰出青年科学基金 (2022)
华为“难题揭榜”火花奖(2023)
1. Junjun Xiang, Zhiwei Yang, Junrui Zhao, Chao Duan, Jingtao Wang,* and Xike Gao.* Poly(vinyl azulene)s: An Emerging Class of Poly(vinyl arene)s. Macromolecules 2024, 57, 7516-7523.
2. Heqi Gao,# Yiming Yao,# Cong Li, Jingtian Zhang, Haoyun Yu, Xiaodi Yang, Jing Shen, Qian Liu, Ruitong Xu, Xike Gao,* and Dan Ding.* Fused Azulenyl Squaraine Derivatives Improve Phototheranostics in the Second Near-Infrared Window by Concentrating Excited State Energy on Non-Radiative Decay Pathways. Angew. Chem. Int. Ed. 2024, 63, e202400372. (# Co-first authors)
3. Jiangao Li, Zhijun Zhang,* Shanshan Jiang, Miaomiao Kang, Deliang Wang, Xue Li, Peng Huang, Xike Gao,* Dong Wang,* and Ben Zhong Tang.* NIR-II Excitable Semiconducting Polymers with AIE Characteristics for Fluorescence-Photoacoustic Imaging-Guided Synergistic Phototherapy. Adv. Funct. Mater. 2024, 34, 2401627.
4. Jiangao Li, Miaomiao Kang,* Zhijun Zhang, Xue Li, Weilin Xu, Dong Wang,* Xike Gao,* and Ben Zhong Tang.* Synchronously Manipulating Absorption and Extinction Coefficient of Semiconducting Polymers via Precise Dual-Acceptor Engineering for NIR-II Excited Photothermal Theranostics. Angew. Chem. Int. Ed. 2023, 62, e202301617.
5. Chengyang Zhang,# Jie Cheng,# Qingqing Wu,# Songjun Hou, Sai Feng, Bo Jiang, Colin J. Lambert,* Xike Gao,* Yueqi Li,* and Jinghong Li.* Enhanced π–π Stacking between Dipole-Bearing Single Molecules Revealed by Conductance Measurement. J. Am. Chem. Soc. 2023, 145, 1617-1630. (# Co-first authors)
6. Yang Wang, Wen Liang Tan, Junjun Xiang, Congwu Ge, Christopher R. McNeill,* and Xike Gao.* Tuning Dipole Orientation of 2,6-Azulene Units in Conjugated Copolymers by C–H Activation Strategy toward High-Performance Organic Semiconductor. ACS Macro Lett. 2023, 12, 487-493.
7. Junjun Xiang, Doan Vu, Mengmeng He, Chao Duan, Congwu Ge, Christopher R. McNeill,* and Xike Gao.* Poly(2, 6-azulene vinylene)s: Azulene Orientation Control and Property Studies. Macromolecules 2023, 56, 9475-9488.
8. Chao Duan, Jianwei Zhang, Junjun Xiang, Xiaodi Yang,* and Xike Gao.* Azulene-Embedded [n]Helicenes (n = 5, 6 and 7). Angew. Chem. Int. Ed. 2022, 61, e202201494.
9. Mingyao Li,# Huanyan Fu,# Boyu Wang,# Jie Cheng,# Weilin Hu, Bing Yin, Peizhen Peng, Shuyao Zhou, Xike Gao,* Chuancheng Jia,* and Xuefeng Guo.* Dipole-Modulated Charge Transport through PNP-Type Single-Molecule Junctions. J. Am. Chem. Soc. 2022, 144, 20797-20803. (# Co-first authors)
10. Bin Hou, Zhuofan Zhou, Cui Yu, Xiao-Song Xue, Jianwei Zhang, Xiaodi Yang, Jing Li, Congwu Ge, Jingtao Wang,* and Xike Gao.* 2,6-Azulene-based Homopolymers: Design, Synthesis, and Application in Proton Exchange Membrane Fuel Cells. ACS Macro Lett. 2022, 11, 680-686.
11. Junjun Xiang, Wen Liang Tan, Jianwei Zhang, Yang Wang, Chao Duan, Christopher R. McNeill, Xiaodi Yang, Congwu Ge, and Xike Gao.* Poly(2,6-azuleneethynylene)s: Design, Synthesis and Property Studies. Macromolecules 2022, 55, 8074-8083.
12. Yiming Yao, Yuan Zhang, Jianwei Zhang, Xiaodi Yang, Dan Ding, Yang Shi,* Huae Xu,* and Xike Gao.* Azulene-Containing Squaraines for Photoacoustic Imaging and Photothermal Therapy. ACS Appl. Mater. Interfaces 2022, 14, 19192-19203.
13. Bin Hou, Jing Li, Zhuofan Zhou, Wen Liang Tan, Xiaodi Yang, Jianwei Zhang, Christopher R. McNeill, Congwu Ge, Jingtao Wang,* and Xike Gao.* Incorporation of Electron-Rich Indacenodithiophene Units into the Backbone of 2,6-Azulene-Based Conjugated Polymers for Proton-Responsive Materials and p-Type Polymeric Semiconductors. ACS Materials Lett. 2022, 4, 392-400.
14. Hanshen Xin, Bin Hou, and Xike Gao.* Azulene-based π-functional materials: design, synthesis, and applications. Acc. Chem. Res. 2021, 54, 1737-1753.
15. Hanshen Xin, Jing Li, Ru-Qiang Lu, Xike Gao,* and Timothy. M. Swager.* Azulene–Pyridine-Fused Heteroaromatics. J. Am. Chem. Soc. 2020, 142, 13598-13605.
16. Honglei Gao,# Congwu Ge,# Bin Hou, Hanshen Xin, and Xike Gao.* Incorporation of 1,3-Free-2,6-Connected Azulene Units into the Backbone of Conjugated Polymers: Improving Proton Responsiveness and Electrical Conductivity. ACS Macro Lett. 2019, 8, 1360-1364. (# Co-first authors)
17. Hanshen Xin, Congwu Ge, Xuechen Jiao, Xiaodi Yang, Kira Rundel, Christopher R. McNeill, and Xike Gao.* Incorporation of 2,6-Connected Azulene Units into the Backbone of Conjugated Polymers: Towards High-Performance Organic Optoelectronic Materials. Angew. Chem. Int. Ed. 2018, 57, 1322-1326.
18. Hanshen Xin, Congwu Ge, Xiaodi Yang, Honglei Gao, Xiaochun Yang, and Xike Gao.* Biazulene diimides: a new building block for organic electronic materials. Chem. Sci. 2016, 7, 6701-6705.
19. Fengjiao Zhang,# Yunbin Hu,# Torben, Schuettfort, Chong-an Di,* Xike Gao,* Christopher R McNeill,* Lars Thomsen, Stefan C B Mannsfeld, Wei Yuan, Henning Sirringhaus, and Daoben Zhu.* Critical Role of Alkyl Chain Branching of Organic Semiconductors in Enabling Solution-Processed N-channel Organic Thin-film Transistors with Mobility of up to 3.50 cm2V-1s-1. J. Am. Chem. Soc. 2013, 135, 2338-2349. (# Co-first authors)
20. Xike Gao,* Chong-an Di,* Yunbin Hu, Xiaodi Yang, Hongyu Fan, Feng Zhang, Yunqi Liu, Hongxiang Li, and Daoben Zhu. Core-expanded naphthalene diimides fused with 2-(1,3-dithiol-2-ylidene)malonitrile groups for high-performance, ambient-stable, solution-processed n-channel organic thin film transistors. J. Am. Chem. Soc. 2010, 132, 3697-3699.