研究员
肖吉昌
职  称: 研究员
学  历: 博士研究生
电  话: 021-54925340
职  务: 课题组长
传  真: 021-64166128
电子邮件: jchxiao@mail.sioc.ac.cn
通信地址: 上海市零陵路345号
个人简历

1988.9.-1992.7.:湖南师范大学化学系,理学学士

1992.7.-1997.7.:湖南省邵阳师范高等专科学校,讲师

1997.8.-2000.8.:上海化工研究院,工学硕士

2000.8.-2003.7.:中国科学院上海有机化学研究所,理学博士

2003.8.-2005.7.:美国爱达荷大学,博士后研究

2005.8. 至今:中国科学院上海有机化学研究所,研究员,课题组长

研究方向

1. 含氟试剂:从易得原料出发,设计新型含氟基团,发展温和、高效的氟(烷基)化试剂

2. 氟化学反应:基于卡宾、叶立德等中间体的产生与转化规律,探索新颖的()化学反应

3. 萃取化学:阐明萃取剂分子结构与萃取性能之间的关系,发展绿色、高效的分离与纯化方法

4. 高纯氟盐:研究高纯氟化物、高纯熔盐的制备、性能与应用


社会任职
获奖及荣誉
代表论著

1. Yang, Xin-Jun; Wang, Zheng; Ni, Qin-Yuan; Lin, Jin-Hong*; Xiao, Ji-Chang*“Copper-Promoted Reductive Cross-Coupling for Cyanodifluoromethylation of (Hetero)aryl Iodides with BrCF2CN” Org. Lett. 2025, 27, 6867-6871.

2. Ni, Qin-Yuan; Zhao, Shiyu; Wu, Chengying; Guo, Yong*; Xiao, Ji-Chang*“Synthesis of trans-2-(Disubstituted-amino)alkenyl Polyoxyperfluoroalkyl Ketones from Tertiary Amines and Perfluoroalkyl Ether Carboxylates Featuring "-CF2O-" Units” Chin. J. Chem.2025, 43, 1847-1854.

3. Sun, Jun; Sun, Yu; Gu, Yu-Cheng; Lin, Jin-Hong*; Xiao, Ji-Chang*“Barton-Kellogg Olefination of (CF3S)2C=S and Subsequent Cyclopropanation for the Installation of Bulky Bis(trifluoromethylthio)methylene Group” JACS Au2025, 5, 1039–1050.

4. Yang, Xin-Jun; Lin, Jin-Hong*; Xiao, Ji-Chang*“BrCF2CN for photocatalytic cyanodifluoromethylation” Nat. Commun.2025, 16, 445. doi.org/10.1038/s41467-024-55797-4

5. Wang, Zheng; Lin, Jin-Hong*; Xiao, Ji-Chang*“Photocatalytic Keto- and Amino-Trifluoromethylation of Alkenes” Org. Lett.2024, 26, 1980-1984.

6. Shi, Hua-Yi; Hu, Jia-Lu; Zheng, Jian; Cai, Ji; Chen, Hongbin*; Lin, Jin-Hong*; Xiao, Ji-Chang*“Kilogram-Scale Synthesis of Ph3P+CF2CO2-Org. Process Res. Dev.2024, 28, 487-491.

7. Liu, Chao; Guo, Yong; Xiao, Ji-Chang*“The legacy of Prof. Qing-Yun Chen: Organofluorine chemistry” Chem2024, 10, 7-18.

8. Zhang, Min; Li, Qiang; Lin, Jin-Hong; Xiao, Ji-Chang*“Difluoroalkylation/Lactonization of Alkenes with BrCF2CO2K via Photoredox Catalysis: Access to α,α-Difluoro-γ-lactones” Chin. J. Chem.2023, 41, 2819-2824.

9. Yang, Yi-Fei; Xiao, Fang; Lin, Jin-Hong; Xiao, Ji-Chang*“The Shuttle of Sulfur Dioxide: Iridium/Copper-Cocatalyzed Trifluoromethylfluorosulfonylation of Alkenes” Adv. Synth. Catal.2023, 365, 301-306.

10. Yu, Donghai; An, Huaying; Du, Ruobing; Li, Linyan; Xu, Shengming; Xiao, Jichang* “A Highly Efficient Heavy Rare Earths Extractant——P227” J. Chin. Soc. Rare Earths2022, 40, 976-987.

11. Zhang, Feng-Xu; Lin, Jin-Hong*; Xiao, Ji-Chang*. “Difluoromethylsulfonyl Imidazolium Salt for Difluoromethylation of AlkenesOrg. Lett.2022, 24, 7611-7616.

12. Zhang, Wei; Deng, Xiaoyun; Zhang, Feng-Xu; Lin, Jin-Hong; Xiao, Ji-Chang*; Liang, Steven H.*. “Synthesis and 18F Labeling of Alkenyl Sulfonyl Fluorides via an Unconventional Elimination Pathway” Org. Lett.2022, 24, 4992-4997.

13. Yang, Yi-Fei; Lin, Jin-Hong*; Xiao, Ji-Chang*Starting from Styrene: A Unified Protocol for Hydrotrifluoromethylation of Diversified AlkenesOrg. Lett.2021, 23, 9277-9282.

14. Zhang, Min; Lin, Jin-Hong; Xiao, Ji-Chang*A Readily Available Trifluoromethylation Reagent and Its Difunctionalization of AlkenesOrg. Lett. 2021,23, 6079-6083.

15. Zhang, Min; Lin, Jin-Hong; Jin, Chuan-Ming*; Xiao, Ji-Chang*“Difluorocarbene-based cyanodifluoromethylationof alkenes induced by a dual-functionalCu-catalyst”Chem. Commun.2021, 57, 2649–2652.

16. Xu, Zhi-Wei;Zhang, Wei; Lin, Jin-Hong*;Jin, Chuan-Ming*; Xiao, Ji-Chang*“Pd-catalyzed transfer of difluorocarbene for three component cross-coupling”Chin. J. Chem.2020, 38, 1647-1650.

17. Zhang, Wei;Gu, Yu-Cheng;Lin, Jin-Hong*; Xiao, Ji-Chang*Dehydroxylative Fluorination of Tertiary AlcoholsOrg. Lett.2020, 22, 6642-6646.

18. Lin, Jin-Hong;Xiao, Ji-Chang*“Fluorinated Ylides/Carbenes and Related Intermediates from Phosphonium/Sulfonium Salts”Acc. Chem. Res.2020, 53, 1498-1510.

19. Zhang, Wei;Lin, Jin-Hong;Zhang, Pengfei*;Xiao, Ji-Chang*“A convenient reagent for the conversion ofaldoximes into nitriles and isonitriles”Chem. Commun.2020, 56, 6221-6224.

10. Zhang, Wei;Lin, Jin-Hong; Wu, Wenfeng*;Cao, Yu-Cai; Xiao, Ji-Chang* “Dehydroxylative trifluoromethylthiolation, trifluoromethylation, and difluoromethylation of alcohols” Chin. J. Chem. 2020, 38, 169-172.

21. Yu, Jiao; Lin, Jin-Hong; Yu, Donghai; Du, Ruobing; Xiao, Ji-Chang*“Oxidation of difluorocarbene and subsequent trifluoromethoxylation”Nat. Commun.2019, 10: 5362 doi: 10.1038/s41467-019-13359-z

22. Zhang, Min; Lin, Jin-Hong; Xiao, Ji-Chang*“Photocatalyzed Cyanodifluoromethylation of Alkenes”Angew. Chem. Int. Ed.2019, 58, 6079-6083.

23. Liu, Zhuo;Long, Jin;Xiao, Xuan;Lin, Jin-Hong*;Zheng, Xing*;Xiao, Ji-Chang*;Cao, Yu-Cai“Ph3P+CF2CO2- as an F- and :CF2 source for trifluoromethylthiolation of alkyl halides”Chin. Chem. Lett.2019, 30, 714-716.

24. Chen, Xin-Lei;Zhou, Sheng-Hua; Lin, Jin-Hong; Deng, Qing-Hai*;Xiao, Ji-Chang*Difluorocarbene-derived trifluoromethylselenolationofbenzyl halides”Chem. Commun.2019, 55, 1410-1413.

25. Zhang, Wei; Chen, Jia; Lin, Jin-Hong*; Xiao, Ji-Chang*; Gu, Yu-Cheng “Rapid Dehydroxytrifluoromethoxylation of Alcohols” iScience2018, 5, 110-117.

26. Chen, Jia; Lin, Jin-Hong; Xiao, Ji-Chang*“Dehydroxylation of alcohols for nucleophilic substitution” Chem. Commun.2018, 54, 7034-7037.

27. Chen, Jia; Lin, Jin-Hong; Xiao, Ji-Chang*“Halogenation through Deoxygenation of Alcohols and Aldehydes” Org. Lett.2018, 20, 3061-3064.

28. Yu, Jiao; Lin, Jin-Hong*; Xiao, Ji-Chang*Reaction of Thiocarbonyl Fluoride Generated from Difluorocarbene with AminesAngew. Chem. Int. Ed.2017, 56, 16669-16673.

29. Duan, Yaya; Lin, Jin-Hong*; Xiao, Ji-Chang*; Gu, Yu-ChengDifluoromethylcarbene for iron-catalyzed cyclopropanationChem. Commun.2017, 53, 3870-3873.

30. Zheng, Jian; Cheng, Ran; Lin, Jin-Hong; Yu, Dong-Hai; Ma, Longle; Jia, Lina; Zhang, Lan; Wang, Lu; Xiao, Ji-Chang*; Liang, Steven H.*An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of 18F-Labeled α-SCF3 Carbonyl CompoundsAngew. Chem. Int. Ed.2017, 56, 3196-3200.

31. Deng, Xiao-Yun; Lin, Jin-Hong; Xiao, Ji-Chang*Pd-Catalyzed Transfer of DifluorocarbeneOrg. Lett.2016, 18, 4384-4387.

32. Deng, Zuyong; Lin, Jin-Hong; Cai, Ji; Xiao, Ji-Chang*Direct Nucleophilic Difluoromethylation of Carbonyl CompoundsOrg. Lett.2016, 18, 3206-3209.

33. Duan, Yaya;Lin, Jin-Hong*;Xiao, Ji-Chang*;Gu, Yu-Cheng “A Trifluoromethylcarbene SourceOrg. Lett.2016, 18, 2471-2474.

34. Yu, Donghai; Du, Ruobing; Xiao, Ji-Chang*pKa Prediction for Acidic Phosphorus-Containing Compounds Using Multiple Linear Regression with Computational DescriptorsJ. Comput. Chem.2016, 37, 1668-1671.

35. Ji, Yun-Long; Luo, Jia-Jia; Lin, Jin-Hong; Xiao, Ji-Chang*; Gu, Yu-Cheng “Cu-catalyzed C-H trifluoromethylation of3-arylprop-1-ynes for the selective construction of allenic Csp2-CF3 and propargyl Csp3-CF3 bonds”Org. Lett.2016, 18, 1000-1003.

36. Deng, Zuyong; Lin, Jin-Hong; Xiao, Ji-Chang*Nucleophilic arylation with tetraarylphosphonium saltsNat. Commun.2016, 7: 10337 doi: 10.1038/ncomms10337.

37. Zheng, Jian; Lin, Jin-Hong; Yu, Liu-Ying; Wei, Yun; Zheng, Xing; Xiao, Ji-Chang*Cross-Coupling between difluorocarbene and carbene-derived in-termediates generated from diazocompounds for the synthesis of gem-difluoroolefinsOrg. Lett.2015, 17, 6150-6153.

38. Zheng, Jian; Wang, Lu; Lin, Jin-Hong; Xiao, Ji-Chang*; Liang, Steven H.*Difluorocarbene-Derived Trifluoromethylthiolation and [18F]Trifluoromethylthiolation of Aliphatic ElectrophilesAngew. Chem. Int. Ed.2015, 54, 13236-13240.

39. Duan, Yaya; Zhou, Bin; Lin, Jin-Hong; Xiao, Ji-Chang*Diastereoselective Johnson-Corey-Chaykovsky trifluoroethylidenationChem. Commun.2015, 51, 13127-13130.

40. Deng, Xiao-Yun; Lin, Jin-Hong; Zheng, Jian; Xiao, Ji-Chang*“Difluoromethylation and gem-difluorocyclopropenation with difluorocarbene generated by decarboxylation”Chem. Commun.2015, 51, 8805-8808.

41. Zheng, Jian; Lin, Jin-Hong; Deng, Xiao-Yun; Xiao, Ji-Chang*1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-Promoted Decompositionof Difluorocarbene and the Subsequent TrifluoromethylationOrg. Lett.2015, 17, 532-535.

42. Zhang, Cheng-Pan; Chen, Qing-Yun; Guo, Yong; Xiao, Ji-Chang*; Gu, Yu-Cheng. “Difluoromethylation and Trifluoromethylation Reagents Derived from Tetrafluoroethane β-Sultone: Synthesis, Reactivity and Applications”Coord. Chem. Rev.2014, 261, 28-72.

43. Zhang, Cheng-Pan; Chen, Qing-Yun; Guo, Yong*; Xiao, Ji-Chang*; Gu, Yu-Cheng “Progress in fluoroalkylation of organic compounds via sulfinatodehalogenation initiation system”Chem. Soc. Rev.2012, 41, 4536-4559.

44. Zhang, Cheng-Pan;Wang, Zong-Ling;Chen, Qing-Yun;Zhang, Chun-Tao;Gu, Yu-Cheng;Xiao, Ji-Chang*. Copper-Mediated Trifluoromethylation of Heteroaromatic Compoundsby Trifluoromethyl Sulfonium SaltsAngew. Chem. Int. Ed.2011, 50, 1896-1900.

承担科研项目情况