46. Y. Zhao, Y. Zhang, T. Wang, R. Pei, Y. Zhao, X. Xue,* X. Wang，* A Thermally Populated Germylene-Based Donor-Acceptor Diradical, Angew. Chem. Int. Ed. 2024, in press, 10.1002/anie.202411180.

45. R. Pei, W. Chang, L. He, T. Wang, Y. Zhao, Y. Liang,* X. Wang,* Main-Group Compounds Selectively Activate Natural Gas Alkanes under Room Temperature and Atmospheric Pressure, Nat. Commun. 2024, in press, NCOMMS202412652.

44. S. Kong,L. Yang,Q. Sun,T. Wang,W. Wang,Y. Zhao,R. Pei, Y. Zhao, H. Cui,* X. Gu,* X. Wang,*Metal-Free Catalytic Formation of a Donor-Acceptor-Donor Molecule and Its Lewis Acid- Adduct Singlet Diradical with High-Efficient NIR-II Photothermal Conversion. Angew. Chem. Int. Ed. 2024, 63, e202400913.

43. S. Tan, X. Wang.* Spin Frustration in Organic Radicals. Angew. Chem. Int. Ed.  2024, DOI: 10.1002/anie.202310147.

42. R. Pei, L. He, Y. Zhao, X. Wang.* The Dynamic Lewis Acid-Carbene Hybrid: Pushing the Electrophilicity of Carbenes to the Limit. J. Am. Chem. Soc. 2023，DOI：10.1021/jacs.3c07923.

41. X. Dong, Q. Luo, Y. Zhao, T. Wang, Q. Sun, R. Pei, Y. Zhao, Y. Zheng* and X. Wang*. A Dynamic Triradical：Synthesis, Crystal Structure and Spin Frustration. J. Am. Chem. Soc. 2023,  DOI:10.1021/jacs.3c04692.

40. M. Liu, X. Yang, Q. Sun, T. Wang, R. Pei, X. Yang, Y. Zhao, L. Zhao,* G. Frenking,* X. Wang,* Lewis Acid-Mediated Radical Stabilization and Dynamic Covalent Bonding: Tunable, Reversible and Photocontrollable. Angew. Chem. Int. Ed. 2023,  DOI:10.1002/anie.202300068.   

39. W. Wang,X. Ma, M. Liu, S. Tang, X. Ding, Y. Zhao, Y. Tan,* M. Kertesz,* X. Wang,* A Triply Negatively Charged Nanographene Bilayer with Spin Frustration. Angew. Chem. Int. Ed. 2023, DOI:10.1002/anie.202217788. 

38. J. Wang, H. Cui, H. Ruan, Y. Zhao, Y. Zhao, L. Zhang,* X. Wang,* The Lewis Acid-Induced Formation of a Stable Diradical with an Intra Molecular Ion Pairing State. J. Am. Chem. Soc. 2022, 144, 18, 7978-7982. 

37. Z. Feng, S. Tang, Y. Su, X. Wang,* Recent Advances in Stable Main Group Element Radicals: Preparation and Characterization. Chem. Soc. Rev. 2022, 51, 5930-5973.  

36. W. Yang, L. Zhang,D. Xiao,R. Feng,W. Wang, Y. Zhao, L. Zhao,* G. Frenking,*X. Wang,* A Diradical Based on Odd-Electron σ-Bonds. Nat. Commun. 2020, 11:1-8. DOI: 1038/s41467-020-17303-4. Highlighted in Nat. Rev. Chem. (Bonding Electrons Happy with Single Life. Nat. Rev. Chem. 2020, 4, 438). 

35. D. Tuo,C. Chen, H. Ruan, Q. Wang, Y. Ao, X. Wang,* D. Wang,* Magnetic Multistability in an Anion Radical Pimer. Angew. Chem. Int. Ed. 2020, 59, 14040-14043. 

34. S. Tang, L. Zhang, H. Ruan, Y. Zhao, X. Wang,* A Magnetically Robust Triplet Ground State Sulfur- Hydrocarbon Diradical Dication. J. Am. Chem. Soc. 2020, 142, 7340-7344. 

33. C. Chen,H. Ruan, Z. Feng, Y. Fang, Y. Zhao, Y. Su,* X. Wang,* Crystalline Diradical Dianions of Azaacenes. Angew. Chem. Int. Ed. 2020, 59, 11794-11799. 

32. Z. Feng,Y. Fang,H. Ruan, Y. Zhao, G. Tan,*X. Wang,* Stable Radical Cation and Dication of an N-Heterocyclic Carbene Stabilized Digallene: Synthesis, Characterization and Reactivity，Angew. Chem. Int. Ed. 2020, 59, 6769-6774. 

31. S. Tang,H. Ruan, R. Feng, Y. Zhao, G. Tan, L. Zhang,* X. Wang*, Tunable Reduction of 2,4,6-Tri(4-pyridyl)-1,3,5-Triazine: from Radical Anion to Diradical Dianion to Radical-Contained Metal-Organic Framework, Angew. Chem. Int. Ed. 2019, 58, 18224-18229. 

30. M. Mondal, L. Zhang, Z. Feng, S. Tang, R. Feng, Y. Zhao, G. Tan,*

H. Ruan,* X. Wang*, Tricoordinate Nontrigonal Pnictogen-Centered Radical Anions: Isolation, Characterization and Reactivity，Angew. Chem. Int. Ed. 2019, 58, 15829-15833. 

29. R. Feng, L. Zhang, H. Ruan, Y. Zhao, G. Tan* and X. Wang*, A Main-Group Element Radical Based One-Dimensional Magnetic Chain, Angew. Chem. Int. Ed. 2019, 58, 6084-6088. 

28. W. Wang, C. Chen, C. Shu, S. Rajca, X. Wang,* A. Rajca,* S = 1 Tetraazacyclophane Diradical Dication with Robust Stability: A Case of Low-Temperature One-Dimensional Antiferromagnetic Chain, J. Am. Chem. Soc. 2018, 140, 7820？7826. 

27. W. Wang, C. Xu, Y. Fang, Y. Zhao, J. Li,* X. Wang,* An Isolable Diphosphene Radical Cation Stabilized by Three-Center Three-Electron π-Bonding with Chromium: End-On versus Side-On Coordination, Angew .Chem. Int. Ed. 2018, 57, 9563–9568. 

26. T. Li, H. Wei, Y. Fang, L. Wang, S. Chen, Z. Zhang, Y. Zhao, G. Tan,* X. Wang,* Elusive Antimony-Centered Radical Cations: Isolation, Characterization, Crystal Structures, and Reactivity Studies, Angew. Chem. Int. Ed.2017, 56, 632. 

25. L. Wang, L. Zhang, Y. Fang, J. Li, C. Chen, Y. Zhao, Y. Song, L. Deng, G. Tan,* X. Wang,* P. P. Power,* Isolable Borane-Based Diradical and Triradical Fused by a Diamagnetic Transition Metal Ion, J. Am. Chem. Soc. 2017, 139, 17723. 

24. G. Tan, X. Wang,* Isolable Bis(triarylamine) Dications: Analogues of Thiele’s, Chichibabin’s, and Müller’s Hydrocarbons, Acc. Chem. Res. 2017, 50, 1997. 

23. W. Wang, J. Li, L. Yin, Y. Zhao, Z. Ouyang, X. Wang,* Z. Wang,* Y. Song,* P. P. Power,* Half-Sandwich Metal Carbonyl Complexes as Precursors to Functional Materials: From a Near-Infrared Absorbing Dye to a Single-Molecule Magnet, J. Am. Chem. Soc. 2017, 139, 12069. 

22. G. Tan, J. Li, Li Zhang, C. Chen, Y. Zhao, X. Wang,* Y. Song,* Y. Zhang,* M. Driess,* The Charge Transfer Approach to Heavier Main-Group Element Radicals in Transition Metal Complexes, Angew. Chem. Int. Ed. 2017, 56, 12741. 

21. T. Li, G. Tan, D. Shao, J. Li, Z. Zhang, Y. Song, Y. Sui, S. Chen, Y. Fang, X. Wang,* Magnetic Bistability in a Discrete Organic Radical, J. Am. Chem. Soc. 2016, 138, 10092-10095. 

20. G. Tan, S. Li, S. Chen, Y. Sui, Y. Zhao, X. Wang,* Isolable Diphosphorus-Centered Radical Anion and Diradical Dianion. J. Am. Chem. Soc. 2016, 138, 6735-6738. 

19. X. Zheng, X. Wang, Z. Zhang, Y. Sui, X. Wang,* P. P. Power,* Access to Stable Metalloradicals with Unsupported and Isomeric Metal-Metal Hemi-Bonds, Angew. Chem. Int. Ed. 2015, 54, 9084–9087 (VIP Paper). 

18. Y. Su, X. Wang, Y. Li, Y. Song, Y. Sui, X. Wang,* Nitrogen Analogues of Thiele’s Hydrocarbon：Closed-Shell vs Open-Shell in the Ground State, Angew. Chem. Int. Ed. 2015, 54, 1634–1637. 

17. S. Zhang, X. Wang, Y. Sui,* X. Wang,* Odd-Electron Bonded Sulfur Radical Cations: X-ray Structural Evidence of a Sulfur-Sulfur Three-Electron σ–Bond, J. Am. Chem. Soc. 2014, 136, 14666–14669. Highlighted by C&E News (“When Three Electrons Are Not a Crowd”, Oct. 27, 2014) 

16. X. Pan, X. Wang, Y. Zhao, Y. Sui, and X. Wang,* A Crystalline Phosphaalkene Radical Anion, J. Am. Chem. Soc. 2014, 136, 9834–9837. 

15. S. Zhang, X. Wang, Y. Su, Y. Qiu, Z. Zhang, and X. Wang,* Isolation and Reversible Dimerization of a Selenium–Selenium Three–Electron σ–Bond, Nat. Commun. 2014, 5, 4127. 

14. Y. Su, X. Zheng, X. Wang, X. Zhang, Y. Sui, and X. Wang,* Two Stable Phosphorus-Containing Four-Membered Ring Radical Cations with Inverse Spin Density Distributions, J. Am. Chem. Soc. 2014, 136, 6251–6254. 

13. Y. Su, X. Wang, X. Zheng, Z. Zhang, Y. Song, Y. Sui, Y. Li, and X. Wang,* Tuning Ground States of Bis(triphenylamine)benzidine Dications by Substituent Effect: From a Closed-Shell Singlet to a Diradicaloid with an Excited Triplet State, Angew. Chem. Int. Ed. 2014, 53, 2857–2861. 

12. X. Zheng, X. Wang, Y. Qiu, Y. Li, C. Zhou, Y. Sui, Y. Li, J. Ma, and X. Wang*, One-Electron Oxidation of an Organic Molecule by B(C₆F₅)₃; Isolation and Structures of Stable Non-para-substituted Triarylamine Cation Radical and Bis(triarylamine) Dication Diradicaloid, J. Am. Chem. Soc. 2013, 135, 14912–14915. 

11. X. Pan, Y. Su, X. Chen, Y. Zhao, Y. Li, J. Zuo, and X. Wang,* Stable Tetraaryldiphosphine Radical Cation and Dication, J. Am. Chem. Soc. 2013, 135, 5561–5564. 

10. X. Pan, X. Chen, T. Li, Y. Li, and X. Wang,* Isolation and X-ray Crystal Structures of Triarylphosphine Radical Cations, J. Am. Chem. Soc. 2013, 135, 3414–3417. 

9. X. Chen, X. Wang, Z. Zhou, Y. Li, Y. Sui, J. Ma, X. Wang,* P. P. Power,* Reversible σ-Dimerizations of Persistent Organic Radical Cations, Angew. Chem. Int. Ed. 2013, 52, 589–592. 

8. X. Chen, X. Wang, Y. Sui,Y. Li, J. Ma,* J. Zuo and X. Wang,* Synthesis,Characterization and Structures of a Persistent Aniline Radical Cation, Angew. Chem. Int. Ed. 2012, 51,11878–11881. 

7. X. Wang,* P. P. Power,* Structural Characterization, Infrared Spectroscopy and Theoretical Calculations for B(C₆F₅)₃ Stabilized Benzene-Ammonia and Benzene-Water Complexes, Angew. Chem. Int. Ed. 2011, 50, 10965–10968. 

独立工作前： 

6. X. Wang, Y. Peng, M. M. Olmstaead, H. Hope, P. P. Power*, A ditetrylyne as a π-Electron Donor: Synthesis and Characterization of [AgAr'GeGeAr']⁺SbF₆^？ and [Ag₂Ar'GeGe(F)Ar']⁺SbF₆^- (Ar'=C₆H₃-2,6(C₆H₃-2,6-Prⁱ₂)2), J. Am. Chem. Soc. 2010, 132, 13150 - 13151. 

5. X. Wang, Y. Peng, Z. Zhu, J. C. Fettinger, P. P. Power*, J. Guo, S. Nagase. Synthesis and characterization of two of the three isomer models of a germanium substituted bicyclo[2.2.0]hexane diradicaloid: stretching the Ge-Ge bond, Angew. Chem. Int. Ed. 2010, 49, 4593 - 4597. 

4. X. Wang, Y. Peng, J. C. Fettinger, M. Olmstead, P. P. Power*, An unsymmetric oxo/imido bridged germanium-centered singlet diradicaloid, J. Am. Chem. Soc. 2009, 131, 14164 – 14165. 

3. X. Wang, Z. Zhu, Y. Peng, H. Lei, J. C. Fettinger, P. P. Power*. Room-temperature reaction of carbon monoxide with a stable diarylgermylene, J. Am. Chem. Soc., 2009, 131, 6912 - 6913. 

2. T. S. Cameron (X-ray), J. Passmore* (Supervisor), X. Wang. The Preparation and X-ray Crystal Structure of [(AgI₂)_n]MF₆ (M=Sb, As): Diiodine Acting as a Donor in the Planar Polymeric [(AgI₂)_n]ⁿ⁺, Angew Chem. Int. Ed. 2004, 43, 1995 – 1998. (作者按姓氏第一个英文字母顺序排列). 

　　Selected as a textbook example：Housecroft & Sharpe，Inorg. Chem. 3rd ed，Pearson，2006，p542. 

1. A. Decken (X-ray), J. Passmore* (Supervisor), X. Wang. Cyclic dimethylsiloxanes as pseudo crown ethers: Syntheses and characterization of Li(Me₂SiO)₅[Al{OC(CF₃)₃}₄], Li(Me₂SiO)₆[Al{OC(CF₃)₃}₄], and Li(Me₂SiO)₆[Al{OC(CF₃)₃Ph}₄], Angew. Chem. Int. Ed. 2006, 45, 2773 - 2777. (作者按姓氏第一个英文字母顺序排列). 

Highlighted in C&E News (April 10, 2006, P54) and Angew Chem. Int. Ed. ( 2007, 46, 4610 - 4613).