杰出青年
李超忠
职  称: 研究员
学  历: 博士研究生
电  话: 021-54925160
职  务: 课题组长
传  真: 021-54925099
电子邮件: clig@mail.sioc.ac.cn
通信地址: 上海市零陵路345号
个人简历

1983.09 – 1988.07  中国科学技术大学应用化学系,学士
1988.09 – 1993.07  中国科学院上海有机化学研究所,博士(导师:袁承业 院士)
1993.08 – 1994.05  中国科学院上海有机化学研究所,助理研究员
1994.06 – 1998.12  美国Iowa State University化学系,博士后
1999.01 – 1999.12  中国科学院上海有机化学研究所,副研究员,课题组长
2000.01 – 至今      中国科学院上海有机化学研究所,研究员,课题组长


研究方向

自由基化学,有机氟化学,金属有机化学,天然产物全合成

社会任职

中国科学技术大学、上海科技大学、华中师范大学兼职博士生导师

获奖及荣誉

1.中国科学院人才计划1999

2.国家杰出青年科学基金(2003

3.中国科学院人才计划(优秀)2003

4.上海市化学化工学会“吴蕴初奖”提名奖(2004

5.国家政府特殊津贴(2006

6.Thieme Chemistry Journal Award2009

7.上海市领军人才(2010

8.Invited Professor, Universite Pierre et Marie Curie2012

9.浙江省“钱江学者”特聘教授(2015

10.科技部重点领域创新团队负责人(2019

11.国家相关人才计划科技创新领军人才(2020

代表论著

1. Jian Wang, Yuchen Zhang, Lin Zhu, Xiao-Song Xue, and Chaozhong Li*, Photoinduced Remote C(sp3)–H Phosphonylation of Amides, Angew. Chem. Int. Ed.2024, 63, e202400856.

2. Yulu Cheng, Jingsen Zhen, Linxiang Chai, Jian Wang, Junyue Yin, Lin Zhu*, and Chaozhong Li*, Photoinduced Decarboxylative Radical Phosphinylation, Angew. Chem. Int. Ed.2024, 63, e202316764.

3. Junyue Yin, Xinru Lin, Linxiang Chai, Cheng-Yu Wang*, Lin Zhu*, and Chaozhong Li*, Phosphonylation of Alkyl Radicals, Chem2023, 9, 1945–1954.

4. Haiwen Xiao, Zhenzhen Zhang, Yewen Fang*, Lin Zhu*, and Chaozhong Li*, Radical Trifluoromethylation, Chem. Soc. Rev.2021, 50, 6308–6319.

5. Benxiang Zhang, Jiayan He, Yi Li, Tao Song, Yewen Fang*, and Chaozhong Li*, Cobalt-Catalyzed Markovnikov-Selective Radical Hydroacylation of Unactivated Alkenes with Acylphosphonates, J. Am. Chem. Soc.2021, 143, 4955–4961.

6. Jiayan He, Guangle Chen, Benxiang Zhang, Yi Li, Jia-Rong Chen, Wen-Jing Xiao, Feng Liu*, and Chaozhong Li*, Catalytic Decarboxylative Radical Sulfonylation, Chem2020, 6, 1149–1159.

7. Benxiang Zhang, Xiaoqing Wang, and Chaozhong Li*, Enantioselective Total Synthesis of (+)-Corymine and (-)-Deformylcorymine, J. Am. Chem. Soc.2020, 142, 3269–3274.

8. Haiwen Xiao, Haigen Shen, Lin Zhu*, and Chaozhong Li*, Copper-Catalyzed Radical Aminotrifluoromethylation of Alkenes, J. Am. Chem. Soc.2019, 141, 11440–11445.

9. Haiwen Xiao, Zhonglin Liu, Haigen Shen, Benxiang Zhang, Lin Zhu*, and Chaozhong Li*, Copper-Catalyzed Late-Stage Benzylic C(sp3)–H Trifluoromethylation, Chem2019, 5, 940–949.

10. Zhonglin Liu, Haiwen Xiao, Benxiang Zhang, Haigen Shen, Lin Zhu,* and Chaozhong Li*, Copper-Catalyzed Remote C(sp3)–H Trifluoromethylation of Carboxamides and Sulfonamides, Angew. Chem. Int. Ed.2019, 58, 2510–2513.

11. Zhonglin Liu, He Chen, Ying Lv, Xinqiang Tan, Haigen Shen, Hai-Zhu Yu*, and Chaozhong Li*, Radical Carbofluorination of Unactivated Alkenes with Fluoride Ions, J. Am. Chem. Soc.2018, 140, 6169–6175.

12. He Chen, Zhonglin Liu, Ying Lv, Xinqiang Tan, Haigen Shen, Hai-Zhu Yu*, and Chaozhong Li*, Selective Radical Fluorination of Tertiary Alkyl Halides at Room Temperature, Angew. Chem. Int. Ed.2017, 56, 15411–15415.

13. Xinqiang Tan, Zhonglin Liu, Haigen Shen, Pei Zhang, Zhenzhen Zhang, and Chaozhong Li*, Silver-Catalyzed Decarboxylative Trifluoromethylation of Aliphatic Carboxylic Acids, J. Am. Chem. Soc.2017, 139, 12430–12433.

14. Haigen Shen, Zhonglin Liu, Pei Zhang, Xinqiang Tan, Zhenzhen Zhang, and Chaozhong Li*, Trifluoromethylation of Alkyl Radicals in Aqueous Solution, J. Am. Chem. Soc.2017, 139, 9843–9846.

15. Yucheng Dong, Zhentao Wang, and Chaozhong Li*, Controlled Radical Fluorination of Poly(meth)acrylic Acids in Aqueous Solution, Nat. Commun.2017, 8, 277.

16. Benxiang Zhang, Xiaoqing Wang, Chao Cheng, Deqian Sun*, and Chaozhong Li*, Total Synthesis of (±)-Corymine, Angew. Chem. Int. Ed.2017, 56, 7484–7487.

17. Benxiang Zhang, Weifeng Zheng, Xiaoqing Wang, Deqian Sun*, and Chaozhong Li*, Total Synthesis of Notoamides F, I, and R and Sclerotiamide, Angew. Chem. Int. Ed.2016, 55, 10435–10438.

18. Chao Liu, Xiaoqing Wang, Zhaodong Li, Lei Cui, and Chaozhong Li*, Silver-Catalyzed Decarboxylative Radical Azidation of Aliphatic Carboxylic Acids in Aqueous Solution, J. Am. Chem. Soc.2015, 137, 9820–9823.

19. Zhaodong Li, Zhentao Wang, Lin Zhu, Xinqiang Tan, and Chaozhong Li*, Silver-Catalyzed Radical Fluorination of Alkylboronates in Aqueous Solution, J. Am. Chem. Soc.2014, 136, 16439–16443.

20. Chengwei Zhang, Zhaodong Li, Lin Zhu, Limei Yu, Zhentao Wang, and Chaozhong Li*, Silver-Catalyzed Radical Phosphonofluorination of Unactivated Alkenes, J. Am. Chem. Soc.2013, 135, 14082–14085.

21. Zhaodong Li, Liyan Song, and Chaozhong Li*, Silver-Catalyzed Radical Aminofluorination of Unactivated Alkenes in Aqueous Media, J. Am. Chem. Soc.2013, 135, 4640–4643.

22. Xuesong Liu, Zhentao Wang, Xiaomin Cheng*, and Chaozhong Li*, Silver-Catalyzed Decarboxylative Alkynylation of Aliphatic Carboxylic Acids in Aqueous Solution, J. Am. Chem. Soc.2012, 134, 14330–14333.

23. Feng Yin, Zhentao Wang, Zhaodong Li, and Chaozhong Li*, Silver-Catalyzed Decarboxylative Fluorination of Aliphatic Carboxylic Acids in Aqueous Solution, J. Am. Chem. Soc.2012, 134, 10401–10404.

24. Zhentao Wang, Lin Zhu, Feng Yin, Zhongquan Su, Zhaodong Li, and Chaozhong Li*, Silver-Catalyzed Decarboxylative Chlorination of Aliphatic Carboxylic Acids, J. Am. Chem. Soc.2012, 134, 4258–4263.

25. Xinqiang Fang, Kun Liu, and Chaozhong Li*, Efficient Regio- and Stereoselective Formation of Azocan-2-ones via 8-Endo Cyclization of α-Carbamoyl Radicals, J. Am. Chem. Soc.2010, 132, 2274–2283.

26. Yewen Fang and Chaozhong Li*, Preference of 4-Exo Ring Closure in Copper-Catalyzed Intramolecular Coupling of Vinyl Bromides with Alcohols, J. Am. Chem. Soc.2007, 129, 8092–8093.

27. Hui Yu, Tao Wu and Chaozhong Li*, Converting Radical Oligomers to a Single Product, J. Am. Chem. Soc.2002, 124, 10302–10303.

承担科研项目情况

主持国家自然科学基金委重大项目 “自由基化学反应的机制与功能”(编号:22193010,起止时间:20221– 202612月)