副研究员
郭勇
职  称: 副研究员
学  历: 博士研究生
电  话: 021-54925462
职  务: 课题组长
传  真: 021-64166128
电子邮件: yguo@sioc.ac.cn
个人网页: http://guoyong.sioc.ac.cn/
通信地址: 上海市零陵路345号
个人简历

教育背景:
1992年-1996年,厦门大学,化学系,本科/学士;
1996年-2001年,中国科学院上海有机化学研究所,博士/研究生,陈庆云(院士);
2002年-2004年,日本冈山大学,自然科学研究科和工学部应用化学科,博士后,宇根山健治(Kenji Uneyama)教授;
2004年-2006年,日本冈山理科大学,高技术研究中心HTRC,博士后,村桥俊一(Shun-Ichi Murahashi)教授;
2006年-2010年,美国爱达荷大学,化学系,博士后 , Jean′ne M. Shreeve教授。
工作经历:
2010年-至今,中国科学院上海有机化学研究所,有机氟化学重点实验室,研究生导师。

研究方向

有机氟化学

社会任职
获奖及荣誉
代表论著

1.Hu, H.; Huang, Y.; Guo, Y. “Henry reaction of fluorinated nitro compounds,” Journal of Fluorine Chemistry, 2012, 133, 108-114.

2.Guo, C.; Wang R.-W.; Guo, Y.; Qing, F.-L. “Palladium-catalyzed direct α-arylation of α-fluoroketones: A straightforward route to α-fluoro-α-arylketones,” Journal of Fluorine Chemistry, 2012, 133, 86-96.

3.Wang, W; Chen, Q.-Y.; Guo, Y. “TiCl4-Promoted Mukaiyama Aldol Reaction of Fluorinated Silyl Enolates for the Construction of a Quaternary Carbon Center,” Synlett, 2011, 2705-2708.

4.Lu, X.-Q.; Guo, Y.; Chen, Q.-Y. “Efficient Synthesis of meso-meso Linked Diporphyrins by Ni(0)-mediated Ullmann Homocoupling,” Synlett, 2011, 77-80.

5.Guo, Y.; Tao, G.-H.; Blumenfeld, A.; Shreeve, J. M. “Impact of Silyl Enol Ether Stability on Palladium-catalyzed Arylations,” Organometallics, 2010, 29, 1818-1823.

6.Guo, Y.; Tao, G.-H.; Zeng, Z.; Gao, H.; Shreeve,J.M.“Energetic Salts Based on Monoanions of N,N-bis[1H-Tetrazol-5-yl]amine and 5,5’-Bis(tetrazole),” Chemistry - A European Journal, 2010, 16, 3753-3762.

7.Wang, R.; Xu, H.; Guo, Y.; Sa, R.; Shreeve, J. M.  “Bis[3-(5-nitroimino-1,2,4-triazolate)-based Energetic Salts: Synthesis and Promising Properties of a New Family of High Density Insensitive Materials,”  Journal of the American Chemical Society, 2010, 132, 11904-11905.

8.Zhang, Y.; Guo, Y.; Joo, Y-H.; Parrish, D. A.; Shreeve, J. M. 3,4,5-Trinitropyrazole-based Energetic Salts, Chemistry – A European Journal, 2010, 16, 10778-10784.

9.Tao, G.-H.; Guo, Y.; Parrish, D. A.; Shreeve, J. M. “Energetic 1,5-Diamino-4H-tetrazolium Nitro-substituted Azolates,” Jounral of Materials Chemistry, 2010, 20, 2999-3005.

10.Wang, R.; Guo, Y.; Sa, R.; Shreeve, J. M. “Nitroguanidine-fused bicyclic guanidinium salts: A family of high density energetic materials,” Chemistry – A European Journal, 2010, 16, 8522-8529.

11.Zhang, Y.; Gao, H.; Guo, Y.; Joo, Y.-H.; Shreeve, J. M. “Hypergolic N,N-Dimethylhydrozimiun Ionic Liquids,” Chemistry – A European Journal, 2010, 16, 3114-3120.

12.Guo, Y.; Tao, G.-H., Joo, Y.-H., Wang, R.; Twanley, B.; Parrish, D. A.; Shreeve, J. M. “Impact Insensitive Dianionic Dinitrourea Salts: The CN4O52- Anion Paired with Nitrogen-Rich Cations,” Energy&Fuels, 2009, 23, 4567?4574.

13.Guo,Y.; Zhao X.; Zhang, D.; Murahashi, S.?I. “Iridium?Catalyzed Reactions of Trifluoromethylated Compounds with Alkenes: A Csp3?H Bond Activation a-to the Trifluoromethyl Group,” Angewandte Chemie, 2009, 121, 2081-2083; Angewandte Chemie Internation Edition, 2009, 48, 2047?2049.

14.Guo, Y.; Twamley, B.; Shreeve J. M. “Pd?Catalyzed Arylation of Silyl Enol Ethers of Substituted a?Fluoroketones,” Organic & Biomolecular Chemistry, 2009, 1716?1722.

15.Zeng, Z.; Guo, Y. Twamley, B.; Shreeve, J. M. “Energetic Polyazole Polynitrobenzenes and Their Coordination Complexes,” Chemical Communications, 2009, 6014?6016.

16.Wang, R.; Guo, Y.; Zeng, Z.; Shreeve, J. M. “Nitrogen?rich Nitroguanidine-functionalized Tetrazolate Energetic Salts,” Chemical Communications, 2009, 2697-2699.

17.Wang, R.; Guo, Y.; Zeng, Z.; Parrish, D. A.; Twamley, B.; Shreeve, J. M. “Furazan?functionalized Tetrazolate?based Salts: A New Family of Insensitive Energetic Materials,” Chemistry – A European Journal, 2009, 15, 2625?2634.

18.Tao, G.?H.; Guo, Y.; Joo, Y.?H; Twamley, B.; Shreeve J. M. “Energetic Nitrogen?rich Salts and Ionic Liquids: 5?Aminotetrazole (AT) as a Weak Acid,” Journal of Materials Chemistry, 2008, 18, 5524–5530.

19.Guo, Y.; Fujiwara, K.; Amii, H.; Uneyama, K. “Selective Defluorination Approach to N?Cbz?3,3?difluoro?2?difluoromethylenepyrrole and its Application to 3,3?Difluoroproline Dipeptide Synthesis,” Journal of Organic Chemistry, 2007, 72, 8523?8526.

20.Guo, Y.; Shreeve, J. M. “Effect of Fluorine on Palladium?catalyzed Cross?coupling Reactions of Aryl Bromides with Trifluoromethyl Aryl Ketones via Difluoroenol Silyl or Monofluoroenol Silyl Ethers,” Chemical Communications, 2007, 3583?3585.

21.Guo, Y.; Gao, H.; Twamley, B.; Shreeve, J. M. “Energetic Nitrogen Rich Salts of N, N?bis[1(2)H?tetrazol?5?yl]amine,” Advanced Materials, 2007, 19, 2884?2888.

22.Guo, Y.; Shreeve, J. M. “Difluoromethylene Compounds as Precursors to Ketones, Carboxylic Acids, Esters, Amides and Carbonates,” Journal of Fluorine Chemistry, 2007, 128, 1280?1285.

23.Guo, Y.; Fujiwara, K.; Uneyama, K. “A Novel Route to Dipeptides via Noncondensation of Amino Acids: 2?Aminoperfluoropropene as a Synthon for Trifluoroalanine Dipeptides,” Organic Letters, 2006, 8, 827?829.

24.Xiao, J.?C.; Duan, J.?X.; Li, A.?R.; Guo, Y.; Chen Q.?Y. “A Simple Method for Preparing Difluorodiodomethane from Difluoro(fluorosulfonyl)acetyl Fluoride,” Collection of Czechoslovak Chemical Communications, 2002, 67, 1320?1324.

25.Guo, Y.; Chen, Q.?Y. “Iododifluoromethyl Alkenes [ICF2CH=CHR]: a Labile System Generated from 1,1?Difluoro?1,3?Diiodoalkanes and its Trapping with Nucleophiles,” Journal of Fluorine Chemistry, 2001, 107, 89?96.

26.Guo, Y.; Chen. Q.-Y “The Reaction and its Product Conversion of Diflourodiiodomethane with Ethyl Vinyl Ether,” Acta Chimica Sinica 《化学学报》, 2001, 59, 1722-1729.

27.Guo, Y.; Chen. Q.-Y “The Electron Transfer Reactions of 1,3-Diiodohexafluoropropane,” Acta Chimica Sinica《化学学报》, 2001, 59, 1730-1734.

28.Guo, Y.; Chen, Q.?Y. “The Reactions of Difluorodiiodomethane with Nucleophiles,” Journal of Fluorine Chemistry, 2000, 102, 105?109.

会议论文

Uneyama, K.; Guo, Y.; Fujiwara, K.; Komatsu, Y. “A Novel Strategy for the Synthesis of Trifluoroalanine Oligopeptides,” Current Fluoroorganic Chemistry, 2007, ACS Symposium Series 949, Chapter 29, 462-476.

承担科研项目情况