研究员
黄正
职  称: 研究员
学  历: 博士研究生
电  话: 021-54925522
职  务: 金属有机化学国家重点实验室主任
传  真: 021-64166128
电子邮件: huangzh@sioc.ac.cn
通信地址: 上海市零陵路345号
个人简历

2023-至今:金属有机化学国家重点实验室主任

2020-2023:金属有机化学国家重点实验室副主任

20122月至今:任中国科学院上海有机化学研究所研究员、课题组长

20098月至20121月:美国伊利诺伊斯大学香槟分校 (UIUC) 化学系从事博士后研究,导师:John F. Hartwig 教授、院士;

20048月至20098月:美国北卡大学教堂山分校(UNC-CH)化学系,获哲学博士学位,导师: Maurice S. Brookhart教授、院士;

20019月至20046月:南开大学化学系,获硕士学位,导师:卜显和教授、院士;

19979月至20016月:南开大学化学系,获学士学位,导师:卜显和教授、院士


研究方向

1. 金属有机化学和催化: 设计合成金属有机络合物,发展分子催化脱氢化学,研究反应机理

2. 烯烃聚合和聚烯烃降解转化:设计过渡金属烯烃聚合催化剂,合成新型高分子材料,研究聚合反应机理;设计催化剂和催化体系,发展聚烯烃温和可控降解和转化新方法和新途径

3. 绿色化学:基于配体设计,发展价格低廉、环境友好、储量丰富的廉价金属催化剂,探索新型有机催化反应。

社会任职
获奖及荣誉

张江国家自主创新示范区杰出创新创业人才2021年)

中国化学会-物理有机化学青年奖(2019年)

陈嘉庚青年科学奖(化学)(2018年)

中国科学院-沙特基础工业公司导师科研奖(2018年和2015年)

中国化学会-中国均相催化青年奖(2017年)

中国化学会-赢创化学创新奖-杰出青年科学家奖(2018年)

上海市第九届青年科技英才(2018年)

中国科学院上海分院十大杰出青年科技创新人才奖(2016年)

上海市青年五四奖章(2015年)

Thieme Chemistry Journal Awardees2015年)

代表论著


1. Gan, L.; # Dong Z.; # Xu H.; Lv H.; Liu G.; Zhang F.;* Huang Z.* Beyond Conventional Degradation: Catalytic Solutions for Polyolefin Upcycling. CCS Chemistry 2024, 6, 313-333.  (#contributed equally)

2. Qian L.; Yu C.; Gan L.; Tang X.; Wang Y.; Liu G.;Leng X.; Sun Z.; Guo Y.; Xue X.;* Huang Z.*Iridium-Catalyzed Enantioselective Transfer Hydrogenation of 1,1-Dialkylethenes with Ethanol: Scope and Mechanism.J. Am. Chem. Soc.2024, 146, 3427-3437.

3. Wang, K.;# Gan, L.; # Wu, Y.; Zhou, M. Liu, G.*; Huang, Z.* “Selective Dehydrogenation of Small and Large Molecules by a Chloroiridium Catalyst” Sci. Adv. 2022, 8, eabo6586. (#contributed equally)

4. Wang, Y.; Huang, Z.; Liu, G.; Huang, Z.* “A New Paradigm in Pincer Iridium Chemistry: PCN Complexes for (De)Hydrogenation Catalysis and Beyond” Acc. Chem. Res.2022, 55, 2145.

5. Zhou, M.-J.; Zhang, L.; Liu, G.; Xu, C.*; Huang, Z.* “Site-Selective Acceptorless Dehydrogenation of Aliphatics Enabled by Organophotoredox/Cobalt Dual Catalysis” J. Am. Chem. Soc.2021, 143, 16470-16485.

6. Huang, Z.;# Wang, Y.; # Leng, X.; Huang, Z.* “An Amine-Assisted Ionic Monohydride Mechanism Enables Selective Alkyne Cis-Semihydrogenation with Ethanol: from Elementary Steps to Catalysis” J. Am. Chem. Soc.2021, 143, 4824-4836. (#contributed equally)

7. Hou, W.; Zhang, D.; Camacho-Fernandez, M. A.; Zhang, Y.; Liu, G.*; Tang, Y.; Guan, Z.*; Huang, Z.* “Double-Linear Insertion Mode of α,ω-Dienes Enabled by Thio-iminoquinoline Iron Catalyst” ACS Catal. 2020, 10, 15092-15103.

8. Tang, X.; Gan, L.; Zhang, X.; Huang, Z.*n-Alkanes to n-Alcohols: Formal Primary C-H Bond Hydroxymethylation via Quadruple Relay Catalysis” Sci. Adv. 2020, 6, eabc6688.

9. Wang, Y.; # Huang, Z.; # Huang, Z.* “Catalyst as colour indicator for endpoint detection to enable selective alkyne trans-hydrogenation with ethanol” Nat. Catal.2019, 2, 529-536. (#contributed equally)

10. Wang, Y.; Huang, Z.; Leng, X.; Zhu, H.; Liu, G.; Huang, Z.* “Transfer Hydrogenation of Alkenes Using Ethanol Catalyzed by a NCP Pincer Iridium Complex: Scope and Mechanism” J. Am. Chem. Soc. 2018,140, 4417-4429.

11. Tang, X.; Jia, X.; Huang, Z. “Thermal, Catalytic Conversion of Alkanes to Linear Aldehydes and Linear Amines” J. Am. Chem. Soc. 2018,140, 4157-4163.

12. Wen, H.; Wan, X.; Huang, Z. “Asymmetric Synthesis of Silicon-Stereogenic Vinylhydrosilanes by Cobalt-Catalyzed Regio- and Enantioselective Alkyne Hydrosilylation with Dihydrosilanes” Angew. Chem. Int. Ed. 2018,57, 6319-6323.

13. Fang, H.; Hou, W.; Liu, G.; Huang, Z. “Ruthenium-Catalyzed Site-Selective Intramolecular Silylation of Primary C–H Bonds for Synthesis of Sila-Heterocycles” J. Am. Chem. Soc. 2017,139, 11601-11609.

14. Jia, X.; Qin, C.; Friedberger, T.; Guan, Z.; Huang, Z. “Efficient and Selective Degradation of Polyethylenes into Liquid Fuels and Waxes under Mild Conditions” Science Advances 2016,2, e1501591.

15. Jia, X.; Huang, Z.* "Conversion of Alkanes to Linear Alkylsilanes Using An Iridium-Iron-Catalysed Tandem Dehydrogenation-Isomerization-Hydrosilylation" Nat. Chem. 2016, 8, 157-161.

16. Yao, W.; Zhang, Y.; Jia, X.; Huang, Z.* "Selective Catalytic Transfer Dehydrogenation of Alkanes and Heterocycles by an Iridium Complex" Angew. Chem. Int. Ed. 2014, 53, 1390-1394. 

17. Zhang, L.; Peng, D.; Leng, X.; Huang, Z.* "Iron-Catalyzed, Atom-Economical, Chemo- and Regioselective Alkene Hydroboration with Pinacolborane" Angew. Chem. Int. Ed. 2013, 52, 3676-3680. 

承担科研项目情况