2022
226.Transition-Metal-Free Controllable Single and Double Difluoromethylene Formal Insertions into C–H Bonds of Aldehydes with TMSCF2Br
Angew.Chem.Int.Ed.2022, e202217088
An Liu, Chuanfa Ni, Qiqiang Xie, Jinbo Hu*
Angew. Chem. Int. Ed. 2022, 62, e202217088.
225.Regioselective Aromatic Perfluoro-tert-butylation Using Perfluoro-tert-butyl Phenyl Sulfone and Arynes
J. Am. Chem. Soc. 2022, 144, 48, 22281–22288
Zhiqiang Wei, Lixian Wen, Kaidi Zhu, Qian Wang, Yanchuan Zhao,* Jinbo Hu*
J. Am. Chem. Soc. 2022, 144, 22281–22288.
224.Synthesis of fluoroalkenes via Julia and Julia-Kocienski olefination reactions
223.Palladium-Catalyzed Defluorinative Coupling of Difluoroalkenes and Aryl Boronic Acids for Ketone Synthesis
Guangwu Sun, Herui Liu, Xiu Wang Wenbo Zhang, Wenjun Miao, Qinyu Luo, Bing Gao,* Jinbo Hu*
Angew. Chem. Int. Ed. 2022. 62. e202213646.
222.Reagent-Controlled Highly Stereoselective Difluoromethylation: Efficient Access to Chiral -Difluoromethylamines from Ketimines
Qinghe Liu, Taige Kong, Chuanfa Ni, Jinbo Hu*
221.Visible-Light-Promoted S-Trifluoromethylation of Thiophenols with Trifluoromethyl Phenyl Sulfone
Zhiqiang Wei, Zhengzhao Lou, Chuanfa Ni, Wei Zhang, Jinbo Hu*
220.Dynamic Kinetic Resolution-Enabled Highly Stereoselective Nucleophilic Fluoroalkylation to Access Chiral β-Fluoro Amines
Qinghe Liu, Taige Kong, Chuanfa Ni, Jinbo Hu*
Org. Lett. 2022, 24, 32, 5982–5987.
219.Controllable Single and Double Difluoromethylene Insertions into C-Cu Bonds: Copper-Mediated Tetrafluoroethylation and Hexafluoropropylation of Aryl Iodides with TMSCF2H and TMSCF2Br
Xiu Wang, Shitao Pan, Qinyu Luo, Qian Wang, Chuanfa Ni, Jinbo Hu*
J. Am. Chem. Soc. 2022, 144, 12202–12211.
(Highlighted in JACS Spotlight)
218.Synthesis of Aryl Perfluorocyclopropyl Ethers via [2 + 1] Cyclopropanation Using TMSCF2Br Reagent
Ran Liu, Jinbo Hu*
Org. Lett. 2022, 24, 3589-3593.
217.Copper-mediated pentafluoroethylation of organoboronates and terminal alkynes with TMSCF3
Shitao Pan, Qiqiang Xie, Xiu Wang, Qian Wang, Chuanfa Ni, Jinbo Hu*
216.SulfoxFluor-Enabled Deoxyazidation of Alcohols with NaN3
JunkaiGuo, Xiu Wang, Chuanfa Ni, Xiaolong Wan, Jinbo Hu*
215.Modified and Scalable Synthesis of N-Tosyl-4-Chlorobenzenesulfonimidoyl Fluoride (SulfoxFluor): Direct Imidation of Sulfinyl Chlorides with Chloramine-T Trihydrate
Renxiang Liu, Xiaocong Zhou, Xinyi He, Yuanqiang Li,* Weiqin Zheng, Xiu Wang, Junkai Guo, Chuanfa Ni,* Jinbo Hu*
Org. Process Res. Dev. 2022, 26, 380−386.
214.Cover Profile: S-(Trifluoromethyl) Benzothioate (TFBT): A KF-Based Reagent for Nucleophilic Trifluoromethylthiolation
Depei Meng, Yichong Lyu, Chuanfa Ni, Min Zhou, Yang Li, Jinbo Hu*
213.S-(Trifluoromethyl)Benzothioate (TFBT): A KF-Based Reagent for Nucleophilic Trifluoromethylthiolation
Depei Meng, Yichong Lyu, Chuanfa Ni, Min Zhou, Yang Li, Jinbo Hu*
212.Difluoromethyl 2-Pyridyl Sulfoximine: A Stereoselective Nucleophilic Reagent for Difluoro(aminosulfinyl)methylation and Difluoro(aminosulfonyl)methylation
Qinghe Liu, Chuanfa Ni, Qian Wang, Depei Meng, Jinbo Hu*
