2025
252.Dehydroxy-perfluoro-tert-butylation of alcohols with PhSO2C(CF3)3 and insights into the structure of the [C(CF3)3]− anion
Kaidi Zhu, Qinyu Luo, Pengcheng Xu, Zhigang Ni, Shuo Sun, Mingyou Hu, Chuanfa Ni, Jinbo Hu*
251.Modular synthesis of CF2-containing compounds with PhSO2CF2H reagent through difluoromethylene radical anion synthon strategy
Shuo Sun, Rulong Jia, Xin Zhou, Zhongyi Wang, Jian Rong, Chuanfa Ni, Jinbo Hu*
Nat. Commun. 2025, 16, 7731-7740.
250.Stereoselective Nucleophilic Di- and Monofluoro(sulfoximidoyl)Methylation of C═C Bonds: Remote Neighboring Group Participation Enables Facile Access to Chiral γ-Fluorinated Amines
Bo Wang, Mengmeng Zheng, Xiaomei Chen, Taige Kong, Qian Wang, Xiao-Song Xue,* Qinghe Liu,* Jinbo Hu*
Angew. Chem. Int. Ed. 2025, 64, e202511400.
249.Nucleophilic trifluoromethylation with CF3H/LiHMDS: probing the nucleophilic reactivity of LiCF3 species
248.A general protocol for efficient construction of perfluoro-tert-butyl alkynes with (perfluoro-tertbutyl)propiolic acid
Zhiqiang Wei, Guangxing Gu, Wei Zhang, Yanchuan Zhao * and Jinbo Hu *
Org. Chem. Front. 2025, 12, 4773–4779.
247.N‑Activation of 2‑PySO2CF2H for Electrophilic Diffuoromethylthiolation of Electron-Rich Heteroarenes
Zhenhao Zhang, Deyun Fu, Yi Luo, Qiqiang Xie, Mingyou Hu, Chuanfa Ni,* Jinbo Hu*
Org. Lett. 2025, 27, 5223-5229.
246.From S‑Fluoroalkylation to Fluoroalkylation−Thiolation: Difunctionalization of Alkenes with Fluoroalkyl Phenyl Sulfones and Thiophenols Enabled by Photoredox Copper Catalysis
