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99. Direct Monofluoromethylation of O-, S-, N-, and P-Nucleophiles with PhSO(NTs)CH2F: Accelerating Effect of α-Fluorine Substitution
Shen, Xiao; Zhou, Min; Ni, Chuanfa; Zhang, Wei; Hu, Jinbo*
Chem. Sci. 2014, 5,117-122
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98. Synthesis of gem-Difluorocyclopropa(e)nes and O-, S-, N-, and P-Difluoromethylated Compounds with TMSCF2Br
Li, Lingchun; Wang, Fei; Ni, Chuanfa; Hu, Jinbo*
Angew. Chem. Int. Ed. 2013, 52, 12390–12394.
(This work was selected as the Hot Paper)
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97. Nucleophilic difluoro(phenylsulfonyl)methylation of carbonyls with PhSO2CF2H reagent in the presence of in situ generated substoichiometric amount of base
Hu, Mingyou; Gao,Bin; Ni, Chuanfa; Zhang, Laijun; Hu, Jinbo*
J. Fluorine Chem. 2013, 155, 52-58.
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96. Highly Stereoselective and One-Pot Synthesis of Tetra-substituted Monofluoroalkenes with Aldehydes and Fluorobis(phenylsulfonyl)methane
Shen, Xiao; Ni, Chuanfa; Hu, Jinbo*
Chin. J. Chem. 2013, 31, 878-884.
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95. Copper-Mediated Trifluoromethylation of Propiolic Acids: Facile Synthesis of α-Trifluoromethyl Ketones
He, Zhengbiao; Zhang, Rui; Hu, Mingyou; Li, Lingchun; Ni, Chuanfa; Hu, Jinbo*
Chem. Sci. 2013, 4, 3478-3483.
(Top 25 most-read Chemical Science articles in 2013)
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94. Copper-Catalyzed Debenzoylative Monofluoromethylation of Aryl Iodides Assisted by the Removable (2-Pyridyl)sulfonyl Group
Zhao, Yanchuan; Ni, Chuanfa, Jiang, Fanzhou; Gao, Bing; Shen, Xiao; Hu, Jinbo*
ACS Catalysis, 2013, 631 – 634
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93. DIAD-Mediated Metal-Free Cross Dehydrogenative Coupling Between Tertiary Amines and α-Fluorinated Sulfones
Huang, Weizhou; Ni, Chuanfa; Zhao, Yanchuan; Hu, Jinbo*
New J. Chem. 2013, 37, 1684.
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92. Silver-Mediated Trifluoromethylation？Iodination of Arynes
Zeng, Yuwen; Zhang, Laijun; Zhao, Yanchuan; Ni, Chuanfa; Zhao, Jingwei; Hu, Jinbo*
J. Am. Chem. Soc. 2013, 135, 2955？2958.
(Highlighted by Synfacts 2013, 9(5), 544.)
(Highlighted by Org. Process R...
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91. Copper-Mediated Fluoroalkylation of Aryl Iodides Enables Facile Access to Diverse Fluorinated Compounds: The Important Role of the (2-Pyridyl)sulfonyl Group
Zhao, Yanchuan; Gao, Bing; Ni, Chuanfa; Hu, Jinbo*
Org. Lett. 2012, 14, 6080-6083.
(Highlighted by Synfacts 2013, 9(3), 312)
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90. Tuning the Reactivity of Difluoromethyl Sulfoximines from Electrophilic to Nucleophilic: Stereoselective Nucleophilic Difluoromethylation of Aryl Ketones
Shen, Xiao; Zhang, Wei; Ni, Chuanfa; Gu, Yucheng; Hu, Jinbo*
J. Am. Chem. Soc. 2012, 134, 16999-17002.
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89. Copper-Mediated Trifluoromethylation of α-Diazo Esters with TMSCF3: The Important Role of Water as a Promoter
Hu, Mingyou; Ni, Chuanfa; Hu, Jinbo*
J. Am. Chem. Soc. 2012, 134, 15257-15260.
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88. Copper-Catalyzed Difluoromethylation of β,γ-Unsaturated Carboxylic Acids: An Efficient Allylic Difluoromethylation
He, Zhengbiao; Hu, Mingyou; Luo, Tao; Li, Lingchun; Hu, Jinbo*
Angew. Chem. Int. Ed. 2012, 51, 11545-11547.
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87. Enantioselective Construction of Fluorinated Tertiary Stereogenic Carbon Centers in Cyclopropanes: A Chiral α-Fluoro Carbanion Strategy
Shen, Xiao; Zhang, Wei; Zhang, Lei; Luo, Tao; Wan, Xiaolong; Gu, Yucheng; Hu, Jinbo*
Angew. Chem. Int. Ed. 2012, 51, 6966-6970.
(Highlighted by Organic Chemistry Portal, Dec. 30, 2013)
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86. From Olefination to Alkylation: In-Situ Halogenation of Julia-Kocienski Intermediates Leading to Formal Nucleophilic Iodo- and Bromodifluoromethylation of Carbonyl Compounds
Zhao, Yanchuan; Gao, Bing; Hu, Jinbo*
J. Am. Chem. Soc. 2012, 134, 5790-5793.
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85. Copper-Catalyzed Di- and Trifluoromethylation of α,β-Unsaturated Carboxylic Acids: A Protocol for Vinylic Fluoroalkylations
He, Zhengbiao; Luo, Tao; Hu, Mingyou; Cao, Yanjing; Hu, Jinbo*
Angew. Chem. Int. Ed. 2012, 51, 3944-3947.
（被《有机化学》亮点介绍）
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