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226.Transition-Metal-Free Controllable Single and Double Difluoromethylene Formal Insertions into C–H Bonds of Aldehydes with TMSCF2Br
An Liu, Chuanfa Ni, Qiqiang Xie, and Jinbo Hu*
Angew.Chem.Int.Ed.2022, e202217088
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225.Regioselective Aromatic Perfluoro-tert-butylation Using Perfluoro-tert-butyl Phenyl Sulfone and Arynes
Zhiqiang Wei, Lixian Wen, Kaidi Zhu, Qian Wang, Yanchuan Zhao*, and Jinbo Hu*
J. Am. Chem. Soc. 2022, 144, 48, 22281–22288
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224.Synthesis of fluoroalkenes via Julia and Julia-Kocienski olefination reactions
QinyuLuo, XiuWang, JinboHu*
Tetrahedron, 2022, 113, 132694
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223.Palladium-Catalyzed Defluorinative Coupling of Difluoroalkenes and Aryl Boronic Acids for Ketone Synthesis
Guangwu Sun, Herui Liu, Xiu Wang, Wenbo Zhang, Wenjun Miao, Qinyu Luo, Bing Gao,* and Jinbo Hu*
Angew.Chem.Int.Ed. 2022, e202213646
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222.Reagent-Controlled Highly Stereoselective Difluoromethylation: Efficient Access to Chiral -Difluoromethylamines from Ketimines
Qinghe Liu , Taige Kong, Chuanfa Ni and Jinbo Hu*
Molecules 2022, 27, 7076. https://doi.org/10.3390/molecules27207076
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221.Visible-Light-Promoted S-Trifluoromethylation of Thiophenols with Trifluoromethyl Phenyl Sulfone
Zhiqiang Wei, Zhengzhao Lou, Chuanfa Ni, Wei Zhang, and Jinbo Hu*
Chem. Commun. 2022, 58, 10024–10027
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220.Dynamic Kinetic Resolution-Enabled Highly Stereoselective Nucleophilic Fluoroalkylation to Access Chiral β-Fluoro Amines
Qinghe Liu, Taige Kong, Chuanfa Ni, and Jinbo Hu*
Org. Lett. 2022, 24, 32, 5982–5987
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219.Controllable Single and Double Difluoromethylene Insertions into C-Cu Bonds: Copper-Mediated Tetrafluoroethylation and Hexafluoropropylation of Aryl Iodides with TMSCF2H and TMSCF2Br
Xiu Wang, Shitao Pan, Qinyu Luo, Qian Wang, Chuanfa Ni, and Jinbo Hu*
J. Am. Chem. Soc.2022, 144, 12202–12211.
(Highlighted in JACS Spotlight)
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218.Synthesis of Aryl Perfluorocyclopropyl Ethers via [2 + 1] Cyclopropanation Using TMSCF2Br Reagent
Ran Liu and Jinbo Hu*
Org. Lett. 2022, 24, 3589-3593
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217.Copper-mediated pentafluoroethylation of organoboronates and terminal alkynes with TMSCF3
Pan, Shitao; Xie, Qiqiang; Wang, Xiu; Wang, Qian; Ni, Chuanfa; Hu, Jinbo*
Chemical Communications, 2022, 58, 5156-5159.
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216.SulfoxFluor-Enabled Deoxyazidation of Alcohols with NaN3
Guo, Junkai; Wang, Xiu; Ni, Chuanfa; Wan, Xiaolong; Hu, Jinbo*
Nature Communications, 2022, 13, e2752.
(J.G. and X.W. contributed equally to this work)
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215.Modified and Scalable Synthesis of N-Tosyl-4-Chlorobenzenesulfonimidoyl Fluoride (SulfoxFluor): Direct Imidation of Sulfinyl Chlorides with Chloramine-T Trihydrate
Liu, Renxiang; Zhou, Xiao-Cong; He, Xin-Yi; Li, Yuan-Qiang;* Zheng, Weiqin; Wang, Xiu; Guo, Junkai; Ni, Chuanfa;* Hu, Jinbo*
Org. Process Res. Dev. 2022, 26, 380-386.
(Featured on the Cover)
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214.Cover Profile: S-(Trifluoromethyl) Benzothioate (TFBT): A KF-Based Reagent for Nucleophilic Trifluoromethylthiolation
Meng, Depei; Lyu, Yichong; Ni, Chuanfa; Zhou, Min; Li, Yang; Hu, Jinbo*
Chemistry-A European Journal 2022, 28, e202200483.
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213.S-(Trifluoromethyl) Benzothioate (TFBT): A KF-Based Reagent for Nucleophilic Trifluoromethylthiolation
Meng, Depei; Lyu, Yichong; Ni, Chuanfa; Zhou, Min; Li, Yang; Hu, Jinbo*
Chemistry-A European Journal 2022,28, e202104395.
(Very important paper)
(Featured on the Cover)(Featured by WileyChem-China)
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212.Difluoromethyl 2-Pyridyl Sulfoximine: A Stereoselective Nucleophilic Reagent for Difluoro(aminosulfinyl)methylation and Difluoro(aminosulfonyl)methylation
Liu, Qinghe; Ni, Chuanfa; Wang, Qian; Meng, Depei; Hu, Jinbo*
CCS Chem.2022,4,3648–3659
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