Before 2021

87. Enantioselective Construction of Fluorinated Tertiary Stereogenic Carbon Centers in Cyclopropanes: A Chiral α-Fluoro Carbanion Strategy

Shen, Xiao; Zhang, Wei; Zhang, Lei; Luo, Tao; Wan, Xiaolong; Gu, Yucheng; Hu, Jinbo*
Angew. Chem. Int. Ed. 2012, 51, 6966-6970.
(Highlighted by Organic Chemistry Portal, Dec. 30, 2013)
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86. From Olefination to Alkylation: In-Situ Halogenation of Julia-Kocienski Intermediates Leading to Formal Nucleophilic Iodo- and Bromodifluoromethylation of Carbonyl Compounds

Zhao, Yanchuan; Gao, Bing; Hu, Jinbo*
J. Am. Chem. Soc. 2012, 134, 5790-5793.
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85. Copper-Catalyzed Di- and Trifluoromethylation of α,β-Unsaturated Carboxylic Acids: A Protocol for Vinylic Fluoroalkylations

He, Zhengbiao; Luo, Tao; Hu, Mingyou; Cao, Yanjing; Hu, Jinbo*
Angew. Chem. Int. Ed. 2012, 51, 3944-3947.
(被《有机化学》亮点介绍)
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84. Palladium-Catalyzed 2,2,2-Trifluoroethylation of Organoboronic Acids and Esters

Zhao, Yanchuan; Hu, Jinbo*
Angew. Chem. Int. Ed. 2012, 51, 1033-1036.
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83. Palladium-Catalyzed Allylation of 2,2,2-Trifluoroethyl Phenyl Sulfone: A Potential 2,2,2-Trifluoroethyl Pronucleophile

Zhang, Wei; Zhao, Yanchuan; Ni, Chuanfa; Mathew, Thomas*; Hu, Jinbo*
Tetrahedron Lett. 2012, 53, 6565-6568.
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82. Nucleophilic Fluoroalkylation of a,β-Unsaturated Carbonyls with α-Fluorinated Sulfones: Investigation of the Reversibility of 1,2-Additions and the Formation of 1,4-Adducts

Shen, Xiao; Ni, Chuanfa; Hu, Jinbo*
HeIv. Chim. Acta, 2012, 95, 2043-2051.
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81. Reactions of Sulfur- and Phosphorus-Substituted Fluoroalkylating Silicon Reagents with Imines and Enamines under Acidic Conditions

Kosobokov, M. D.; Dilamn, A. D.*; Struchkova, M. I.; Belyakov, P. A.; Hu, Jinbo
Journal of Organic Chemistry, 2012, 77, 2080-2086.
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80. Nucleophilic Difluoromethylation of C=N Bonds in Heterocycles with Difluoromethyl Silane Reagents

Huang, Weizhou; Ni, Chuanfa; Zhao, Yanchuan; Zhang, Wei; Dilman, Alexander, D.; Hu, Jinbo*
Tetrahedron, 2012, 68, 5137-5144.
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79.Difluoro(phenylchalcogen)methylation of aldehydes, ketones, and imines with S-, Se-, and Te-containing reagents PhXCF2H (X = S, Se, Te)

Hu, Mingyou; Wang, Fei; Zhao, Yanchuan; He, Zhengbiao; Hu, Jinbo*
J. Fluorine Chem. 2012, 135, 45-58.
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78.Nucleophilic Difluoromethylation of N,N-Acetals with TMSCF2SO2Ph Reagent Promoted by Trifluoroacetic Acid: A Facile Access to α-Difluoromethylated Tertiary Amines

Huang, Weizhou; Ni, Chuanfa; Zhao, Yanchuan; Gao, Bing; Hu, Jinbo*
J. Fluorine Chem. 2012, 143, 161-166.
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77.Selective Fluoroalkylation of Organic Compounds by Tackling the ‘Negative Fluorine Effect’

Zhang, Wei; Ni, Chuanfa; Hu, Jinbo*
Top. Curr. Chem. 2012, 308, 25-44.
"负氟效应(Negative Fluorine Effect)"概念被高等教育出版社出版的《中级有机化学——反应与机理》收录
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76.Efficient and Direct Nucleophilic Difluoromethylation of Carbonyl Compounds and Imines with Me3SiCF2H at Ambient or Low Temperature

Zhao, Yanchuan; Huang, Weizhou; Zheng, Ji; Hu, Jinbo*
Org. Lett. 2011, 13, 5342-5345.
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75.Polymer Electrolyte Membranes Based on Poly(norbornene)s with Pendant Difluoroalkyl Sulfonic Acids (以二氟烷基磺酸修饰的降冰片烯为基础的聚合物电解质薄膜的制备)

Zhao, Yanchuan (赵延川); Lijun Zhang (张丽君); Guofeng Xu (许国峰); Ji Zheng (郑吉); Jinbo Hu*(胡金波)
Science China: Chemistry (中国科学?化学), 2011, 41, 1833-1839.
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74.Difluoromethylation of O-, S-, N-, C-Nucleophiles Using Difluoromethyltri(n-butyl)ammonium Chloride as a New Difluorocarbene Source

Wang, Fei; Huang, Weizhou; Hu, Jinbo*
Chin. J. Chem.,2011, 29, 2717-2721.
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73.Synthesis of gem-Difluorinated Cyclopropanes and Cyclopropenes:Trifluoromethyltrimethylsilane as a Difluorocarbene Source

Wang, Fei; Luo, Tao; Hu, Jinbo*, Wang, Ying; Krishnan, Hema S.; Jog, Parag V.; Ganesh, Somesh, K.; Prakash, G. K. Surya*, Olah, George A.
Angew. Chem. Int. Ed. 2011, 50, 7153-7157.
(Referred to as ...
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