Publications

Preprints


53. Wu, Y.*; Qian, H.-Y.; Zou, J.-Y.; Wu, Q.-Y.; Nie, X.-X.; Zheng, L.; Wang, P.* Rh-Catalyzed Enantioselective Hydrosilylation of Unactivated Alkenes. Preprint: Chemrxiv 2024, DOI: 10.26434/chemrxiv-2024-3tlq2.


52. Chen, S.-H.; Zhang, S.; Chen, Z.-Y.; Wu, Y.; Wang, P.* The Development and Application of SPSiBox Ligands: Cu-Catalyzed Enantioselective Carbene Insertion of Ge–H Bonds. Preprint: Chemrxiv 2024, DOI: 10.26434/chemrxiv-2024-105l3.

                   

Peer-ReviewedPublications   

   


51. She, L.-Q.; Wang, D.-M.; Wu, Y.; Wang, P.* Ligand-Enabled Ni-Catalyzed Dicarbofunctionalization of Alkenyl Alcohols. Chem Catal. 2025, in press. (Preprint: Chemrxiv 2024, DOI: 10.26434/chemrxiv-2024-hrv2f.)


50. Wang, J.-P.; Liu, T.; Wu, Y.; Wang, P.* Pd-Catalysed Migratory 1,1-Cycloannulation Reaction of Alkenes.J. Am. Chem. Soc.2024, DOI: 10.1021/jacs.4c14153. (Preprint: Chemrxiv 2024, DOI: 10.26434/chemrxiv-2024-jxsfc.)


49. Wang, D.-M.; Shan, H.-M.; She, L.-Q.; He, Y.-Q.; Wu, Y.; Tang, Y.; Xu, L.-P.*; Wang, P.* Ligand-Enabled Ni-Catalysed Dicarbofunctionalisation of Alkenes with Diverse Native Directing Groups. Nat. Commun. 2024, 15, 10333.(Preprint: Chemrxiv 2024, DOI: 10.26434/chemrxiv-2024-h02wc.)


48. Zheng, L.*; Li, Y.-C.; Wu, Y.; Wang, P.* Photoinduced Copper-Catalyzed Cross-Coupling of Acylsilanes with Heteroarenes via Bimetallic Relay. Adv. Sci.2024, 11, 2409457. (Preprint: Chemrxiv 2024, DOI: 10.26434/chemrxiv-2024-6x3q7.)


47. Wang, D.-M.; He, Y.-Q.; Wu, Y.; Tang, Y.; Wang, P.* Construction of Lactones via Ligand-Enabled Ni-Catalyzed Alkene Hydroxylarylation/Lactonization. Org. Lett.2024, 26, 8171–8176.


46. Shen, H.-C.; Li, J.-J.; Wang, P.*, Yu, J.-Q.* meta-C–H Functionalization of Phenylethyl and Benzylic Alcohol Derivatives via Pd/NBE Relay Catalysis. Chem. Sci. 2024, 15, 15819–15824.



45. Li, Z.-D.; Ren, F.; Wu, Y.; Li, J.-J.; Luo, J.*; Wang, P.* Development and Application of SPOSiPs: A Class of Diphosphine Ligands Based on SPOSiOL. Org. Lett.2024, 26, 7436–7441.


44. Wang, J.-P.; Wang, P.*Phosphine Ligand-Dependent Nickel-Catalyzed Regiodivergent Isomerization of Alkenes. Chem Catal.2024, 4, 101089.


43. Cao, Z.-W.; Zhang, J.-C.; Wang, J.-T.; Li, L.; Chen, X.-Y.; Jin, S.; Cao, Z.-Y.*; Wang, P.* Palladium-Catalyzed Hiyama-Type Coupling of Thianthrenium and Phenoxathiinium Salts. Org. Lett. 2024, 26, 6681−6686.


42. Wang, D.-M.; Yang, L.; Chen, D.-P.; Wu, Y.; Tang, Y.; Wang, P.*Pd(II)-Catalyzed 1,2-Oxyarylation of Alkenes with O-Acylhydroxylamines as the Oxygen Source. Org. Lett.2024,26, 3691–3696.


41. Gou, F.-H.; Ren, F.; Wu, Y.; Wang, P.* Catalytic Kinetic Resolution of Monohydrosilanes via Rhodium-Catalyzed Enantioselective Intramolecular Hydrosilylation. Angew. Chem. Int. Ed.2024, 63, e202404732. (Preprint: Chemrxiv 2024, DOI: 10.26434/chemrxiv-2024-7wxck.)


40. Hu, J.-L.; Wu, Y.; Gao, Y.; Wang, Y.*; Wang, P.* Recent Advances in Catalytic Nitrogen–Nitrogen Bond Formation Reactions. ACS Catal. 2024,14, 5735–5778.


39. Zhao, J.-H.; Zheng, L.; Zou, J.-Y.; Zhang, S.-Y.; Shen, H.-C.; Wu, Y.; Wang, P.* Construction of Si-Stereogenic Silanols by Pd-Catalyzed Enantioselective C–H Alkenylation. Angew. Chem. Int. Ed.2024, 63, e202402612. (Preprint: Chemrxiv 2023, DOI: 10.26434/chemrxiv-2023-57wf2.)


38. Liu, S.; Chen, Y.-S.; Wu, Y.; Wang, P.* Pd-Catalyzed Intermolecular Si–O Formation via Si–C Activation. Sci. China Chem.2024, DOI: 10.1007/s11426-024-1951-0. (Preprint: Chemrxiv 2023, DOI: 10.26434/chemrxiv-2023-z5bsp.)


37. He, H.-D.; Chitrakar, R.; Cao, Z.-W.; Wang, D.-M.; She, L.-Q.; Zhao, P.-G.; Wu, Y.; Xu, Y.-Q.; Cao, Z.-Y.*; Wang, P.* Diphosphine Ligand-Enabled Ni-Catalyzed Chelate-Assisted Inner-Selective Migratory Hydroarylation of Alkenes. Angew. Chem. Int. Ed. 2024, 63, e202313336. 

(Preprint: Chemrxiv 2023, 10.26434/chemrxiv-2023-rq8c6. )      


36. Kuang, X.; Li, J.-J.; Liu, T.; Ding, C.-H.; Wu, K.; Wang, P.*; Yu, J.-Q.* Cu-Mediated Enantioselective C–H Alkynylation of Ferrocenes with Chiral BINOL Ligands. Nat. Commun.2023, 14, 7698.                                          

35. Wu, Y.; Zheng, L.; Wang, Y.*; Wang, P.* Catalytic Asymmetric Synthesis of Silicon-Stereogenic Organosilanes. Chem 2023, 9, 3461–3514.                          

      


34. Li, M.-H.; Cao, Z.-Y.*; Wang, P.* Programmatic Functionalization of Multihydrosilanes by Hydrogen-Atom-Transfer Photocatalysis.Chem Catal.2023, 3, 100674.
         
33. Wang, D.-M.; She, L.-Q.; Yuan, H.; Wu, Y.; Wang, P.* Ligand-Enabled Ni(II)-Catalyzed Hydroxylarylation of Alkenes with Molecular Oxygen. Angew. Chem. Int. Ed.2023, 62, e202304573 . 
(Preprint:Chemrxiv2023, DOI: 10.26434/chemrxiv-2023-0kcb5.)                            

      


32. Li, H.; Zhao, P.-G.; Wang, C.-Y.; Zhang, R.-Y.; Li, J.-J.; Wu, Y.; Wang, P.* SPSiPs, A Class of Diphosphine Ligands Based on SPSiOL with a Large Dihedral Angle. Org. Lett. 2023, 25, 3859–3863.
(Preprint: Chemrxiv 2023, DOI: 10.26434/chemrxiv-2023-8k18l.)
    
             
31. Li, J.-J.; Zhao, J.-H.; Shen, H.-C.; Wu, K.; Kuang, X.; Wang, P.*; Yu, J.-Q.* Atroposelective Remote meta-C–H Activation. Chem 2023, 9, 1452–1463.
Highlighted byChem2023, 9, 1347–1349.
Highlighted by Synfacts 2023, 19, 0886.

30. Kuang, X.; Ding, C.-H.; Wu, Y.; Wang, P.* Catalytic Enantioselective Preparation of Chiral Allylsilanes. Chin. J. Org. Chem. 2023, 43, 3367–3387.
        

          


29. Chen, X.-Y.; Li, Y.-N.; Wu, Y.; Bai, J.-H.; Guo, Y.-L.*; Wang, P.* Cu-Mediated Thianthrenation and Phenoxathiination of Arylborons.J. Am. Chem. Soc.2023, 145, 10431–10440. 
(Preprint: Chemrxiv 2022, DOI: 10.26434/chemrxiv-2022-4jd98.)

      


28. Chen, X.-Y.; Kuang, X.; Wu, Y.*; Zhou, J.*; Wang, P.* Thianthrene Radical Cation as a Transient SET Mediator: Photoinduced Thiocyanation and Selenocyanation of Arylthianthrenium Salts. Chin. J. Chem. 2023, 41, 1979–1986. 
(Preprint: Researchsquare2023,  DOI:10.21203/rs.3.rs-2327792/v1.)


27. Meng, G.; Wang, Z.; Chan, H. S. S.; Chekshin, N.; Li, Z.; Wang, P.; Yu, J.-Q.* Dual-Ligand Catalyst for the Nondirected C–H Olefination of Heteroarenes. J. Am. Chem. Soc.2023, 145, 8198–8208.

26. Ye, Z.-H.; Gou, F.-H.; Wu, Y.; Li, C.-Y.*; Wang, P.* Diverse Synthesis of Alkenylsilanes via d-Catalyzed Alkenyl C–H Silylation. Org. Lett. 2023, 25, 2145–2150.


25. Liu T.; Mao, X.-R.; Song, S. Chen, Z.-Y.; Wu, Y.; Xu, L.-P.*; Wang, P.* Enantioselective Nickel-Catalyzed Hydrosilylation of 1,1- Disubstituted Allenes. Angew. Chem. Int. Ed. 2023, 62, e202216878.
Highlighted by Chin. J. Org. Chem.2023, 43, 1213–1214.


24. Zheng L.; Guo, X.; Li, Y.-C.; Wu, Y.; Xue, X.-S.*; Wang, P.* Cu/SaBox-Catalyzed Photoinduced Coupling of Acylsilanes with Alkynes. Angew. Chem. Int. Ed.2023, 62,  e202216373.


23. Wang, D.-M.; She, L.-Q.; Wu, Y.; Zhu, C.; Wang, P.* Ligand-Enabled Ni-Catalyzed Hydroarylation and Hydroalkenylation of Internal Alkenes with Organoborons. Nat. Commun.2022, 13, 6878.


22. Dong, Z.-Y.; Zhao, J.-H.; Wang, P.*; Yu, J.-Q.* MPAI-Ligand Accelerated Pd-Catalyzed C(sp3)–H Arylation of Free Aliphatic Acids. Org. Lett.2022, 24, 7732–7736.                    

21. Wang, J.-P.; Song, S.; Wu, Y.; Wang, P.* Construction of Azaheterocycles via Pd-Catalyzed Migratory Cycloannulation Reaction of Unactivated Alkenes. Nat. Commun.2022,13, 5059.


20. Chen, X.-Y.; Wu, Y.; Wang, P.* Recent Advances in Thianthrenation /PhenoxathiinationEnabled Site-Selective Functionalization of Arenes. Synthesis, 2022, 54, 3928–3940.


19. Wu, Y.; Wang, P.* Silicon-Stereogenic Monohydrosilane: Synthesis and Applications. Angew. Chem. Int. Ed.2022, 61, e202205382. 

      
18. Chen, H.; Wu, Y.; Yu, Y.; Wang, P.* Pd-Catalyzed Isomerization of Alkenes. Chin. J. Org. Chem. 2022, 42, 742–757.

   


17. Huang, Y.-H.; Wu, Y.; Zhu, Z.; Zheng, S.; Ye, Z.; Peng, Q.*; Wang, P.* Enantioselective Synthesis of Silicon-Stereogenic Monohydrosilanes by Rhodium-Catalyzed Intramolecular Hydrosilylation. Angew. Chem. Int. Ed. 2022,61,e202113052.
Highlighted by Chin. J. Org. Chem.2022, 42, 918–920.


16. Yang, L.; Xu, W.-Q.; Liu, T.; Wu, Y.; Wang, B.-Q.*; Wang, P.* Concise Synthesis and Application of Enantiopure Spirobiphenoxasilin-Diol and Its Related Chiral Ligands. Chem. Commun. 2021, 57, 13365–13368.


15. Zhang, Y.-L.; Wang, G.-H.; Wu, Y.; Zhu, C.-Y.*; Wang, P.* Construction of -Amino Azines via Thianthrenation Enabled Photocatalyzed Hydroarylation of Azine-Substituted Enamides with Arenes. Org. Lett. 2021, 23, 8522–8526.


14. Zheng, L.; Nie, X.-X.; Wu, Y.; Wang, P.* Construction of Si-Stereogenic Silanes via C-H Activation Approach. Eur. J. Org. Chem. 2021,  6006–6014.
This article also appears in: Silicon Chemistry in Organic Synthesis


13. Zheng, L.; Wang, P.* Efficient Synthesis of Diarylmethanamines via Transition-Metal-Free Double-Insertive Coupling of Isocyanides with Arylboronic Acids. Chin. J. Org. Chem. 2021, 41, 1272–1273. 


12. Wang, D.-M.; Feng, W.; Wu, Y.; Liu, T.; Wang, P.* Redox-Neutral Nickel(II) Catalysis: Hydroarylation of Unactivated Alkenes with Arylboronic Acids. Angew. Chem. Int. Ed.2020,59,  20399–20404.
Highlighted by Synfacts, 2020, 16, 1316. 


11. Chen, H.-C.; Chang, X.* A Journey to SPSiOL, a  New Type of Chiral Ligand Scaffold. Chin. J. Chem.2020, 38, 1203–1204.


10. Chang, X.; Ma, P.-L.; Chen, H.-C.; Li, C.-Y.*; Wang, P.* Asymmetric Synthesis and Application of Chiral Spirosilabiindanes. Angew.  Chem. Int. Ed.2020,59, 8937–8940. 

9. Nie, X.-X.; Huang, Y.-H.; Wang, P.* Thianthrenation Enabled  -Arylation of Carbonyl Compounds with Arenes. Org.  Lett. 2020, 22, 7716-7720.  


8. Zhang, Y.-L.; Yang, L.; Wu, J.; Zhu, C.*; Wang, P.* Vinyl Sulfonium Salts as the Radical Acceptor for Metal-Free Decarboxylative Alkenylation. Org.  Lett.2020, 22, 7768-7772.


7. Wu, Y.; Huang, Y.-H.; Chen, X.-Y.; Wang,P.* Site-Selective Silylation of Simple Arenes Mediated by Thianthrene S-Oxide. Org.  Lett.2020, 22, 6657–6661.


6. Chen, X.-Y.; Wu, Y.; Zhou, J.*; Wang, P.* Pd-Catalyzed Site-Selective Borylation of Simple Arenes via Thianthrenation. Chin.  J.  Chem.2020, 38, 1269–1272. 


5. Li, J.-J.; Wang, C.-G.; Yu, J.-F.; Wang, P.*; Yu, J.-Q.* Cu-Catalyzed C-H Alkenylation of Benzoic Acid and Acrylic Acid Derivatives with Vinyl Boronates. Org.  Lett. 2020, 22, 4692-4696.
  
4. Chen, X.-Y.; Nie, X.-X.; Wu, Y.; Wang, P.* Para-Selective Arylation and Alkenylation of Monosubstituted Arenes Using Thianthrene S-Oxide as a Transient Mediator. Chem. Commun.2020, 56, 5058–5061.


3. Wu, J.; Wang, Z.; Chen, X.-Y.; Wu, Y.; Wang, D.; Peng, Q.*; Wang, P.* Para-Selective Borylation of Monosubstituted Benzenes Using a Transient Mediator. Sci. China Chem.2020, 63, 336–340.
(Preprint: Chemrxiv2019, DOI: 10.26434/chemrxiv.8148725.v3.)


2. Yu, J.-F.; Li, J.-J.; Wang, P.*; Yu, J.-Q.* Cu-Mediated Amination of (Hetero)Aryl C–H bonds with NH Azaheterocycles. Angew.  Chem. Int. Ed.2019, 58, 18141–18145. 
  
1. Chen, X.-Y.; Wu, Y.; Zhou, J.; Wang, P.*; Yu, J.-Q.* Synthesis of -Arylethenesulfonyl Fluoride via Pd-Catalyzed Nondirected C–H Alkenylation. Org.  Lett. 2019,  21, 1426–1429.
  

Supervised Work (Before 2018)

21.Yang, G.; Zhu, D.; Wang, P.; Tang, R.-Y.; Yu, J.-Q.* Remote C−H Activation of Various N-Heterocycles Using a Single Template. Chem. Eur. J.2018, 24, 3434–3438.
20. Farmer, M. E.; Wang, P.; Shi, H.; Yu, J.-Q.* Palladium Catalyzed meta-C–H Functionalization of Masked Aromatic Aldehydes. ACS Catal.2018, 8, 7362–7367.
19. Wang, P.; Verma, P.; Xia, G.; Shi, J.; Qiao, J. X.; Tao, S.; Cheng, P. T. W.; Poss, M. A.; Farmer, M. E.; Yeung, K.-S.; Yu, J.-Q.* Ligand-Accelerated Non-Directed C‒H Functionalization of Arenes. Nature2017, 551, 489–493.
18. Cheng, G.; Wang, P.; Yu, J.-Q.* meta-C‒H Arylation and Alkylation of Benzylsulfonamide Enabled by a Pd(II)/Isoquinoline Catalyst. Angew. Chem. Int. Ed. 2017, 56, 8183–8186.
17. Wang, P.; Farmer, M. E.; Yu, J.-Q.* Ligand-Promoted meta-C–H Functionalization of Benzylamines. Angew. Chem. Int. Ed.2017, 56, 5125–5129.
16. Li, G.-C.; Wang, P.; Farmer, M. E.; Yu, J.-Q.* Ligand-Enabled Auxiliary-Free meta-C–H Arylation of Phenylacetic Acids. Angew. Chem. Int. Ed.2017, 56, 6874–6877.
15. Fu, H.; Shen, P.-X.; He, J.; Zhang, F.; Li, S.; Wang, P.; Liu, T.; Yu, J.-Q.* Ligand-Enabled Alkynylation of C(sp3)-H Bonds with Pd(II) Catalysts. Angew. Chem. Int. Ed.2017, 129, 1899–1902.
14. Ding, Q.; Ye, S.; Cheng, G.; Wang, P.; Farmer, M. E.; Yu, J.-Q.* Ligand-Enabled meta-Selective C–H Arylation of Nosyl Protected Phenethylamines, Benzylamines and 2-Aryl Anilines.J. Am. Chem. Soc.2017,139, 417–425.
13. Wang, P.; Li, G.-C.; Jain, P.; Farmer, M. E.; He, J.; Yu J.-Q.* Ligand-Promoted meta-C–H Amination and Alkynylation.J. Am. Chem. Soc.2016, 138, 14092–14099.
12. Wang, P.; Farmer, M. E.; Huo, X.; Jain, P.; Shen, P.-X.; Ishoey, M.; Bradner, J. E.; Wisniewski, S. R.; Eastgate, M. E.; Yu, J.-Q.* Ligand-Promoted meta-C–H Arylation of Anilines, Phenols, and Heterocycles. J. Am. Chem. Soc.2016, 138, 9269–9276.
11. Shi, H.; Wang, P.; Suzuki, S.; Farmer, M. E.; Yu J.-Q.* Ligand Promoted meta-C–H Chlorination of Anilines and Phenols.J. Am. Chem. Soc.2016, 138, 14876–14879.
10. Shen, P.-X.; Wang, X.-C.; Wang, P.; Zhu, R.-Y.; Yu, J.-Q.* Ligand-Enabled meta-C–H Alkylation and Arylation Using a Modified Norbornene.J. Am. Chem. Soc.2015, 137, 11574–11577.
9. Feng, L.-W.; Wang, P.; Wang, L.-J.; Tang, Y.* Copper(I)/SaBOX Catalyzed Highly Diastereo- and Enantioselective Cyclopropanation of cis-1,2-Disubstituted Olefins with α-Nitrodiazoacetates. Sci. Bull. 2015, 60, 210–215.
8. Yang, G.; Lindovska, P.; Zhu, D.; Kim, J.; Wang, P.; Tang, R.-Y.; Movassaghi, M.; Yu, J.-Q.* Pd(II)-Catalyzed meta-C–H Olefination, Arylation, and Acetoxylation of Indolines using a U-Shaped Template.J. Am. Chem. Soc.2014, 136, 10807–10813.
7. Wang, P.;Liao, S.; Zhu, J.-B.; Tang, Y.* Double g-Alkylation of Allylic Phosphorus Ylides: a Unique Access to Oxa-bicyclic[3.3.0] Diene Skeletons. Chem. Commun.2014, 50, 808–810.
6. Wang, P.; Ling, L.; Zhu, J.-B.; Liao, S.; Wang, S. R.; Li, Y.-X.; Tang, Y.* Reactions of Iron Carbenes with α,β-Unsaturated Esters by Using an Umpolung Approach: Mechanism and Applications. Chem. Eur. J. 2013, 19, 6766–6773.
5. Wang, P.; Liao, S.; Wang, S. R.; Gao, R.-D.; Tang, Y.* Reaction of Trisubstituted Alkenes with Iron Porphyrin Carbenes: Facile Synthesis of Tetrasubstituted Dienes and Cyclopentadienes. Chem. Commun.2013, 49, 7436–7438.
4. Zhu, J.-B.; Wang, P.; Liao, S.; Tang, Y.* PPh3-Mediated Intramolecular Conjugation of Alkyl Halides with Electron-Deficient Olefins: Facile Synthesis of Chromans and Relevant Analogues. Chem. Commun. 2013, 49, 4570–4572.
3. Zhu,J.-B.; Wang, P.; Liao, S.; Tang, Y.* Ylide Hydrolysis in Tandem Reactions: a Highly Z/E-Selective Access to 3-Alkylidene Dihydrobenzofurans and Related Analogues.Org. Lett.2013, 15, 3054–3057.
2. Wang, P.; Liao, S.; Zhu, J.-B.; Tang, Y.* Iron-Catalyzed Three-Component Reaction: Multiple C–C Bond Cleavages and Reorganizations. Org. Lett.2013, 15, 3606–3609.
1. Wang, P.; Liu, C.-R.; Sun, X.-L.; Chen, S.-S.; Li, J.-F.; Xie, Z.*; Tang, Y.* A Newly-Designed PE-Supported Arsine for Efficient and Practical Catalytic Wittig Olefination. Chem. Commun.2012, 48, 290–292.

Book Chapters

1. Liao, S.; Wang, P.; Tang, Y. “Covalent Activations: Ylides” in Comprehensive Enantioselective Organocatalysis: Catalysts, Reactions, and Application; P. Dalko, Ed.; Wiley-VCH&Sons: Weinheim, Germany, 2013.


Patents

6. 王鹏, 常鑫; 一种硅螺环化合物的制备方法, 专利申请号:CN 202010117720.1
5. 王鹏, 常鑫, 马培龙; 螺双二氢苯并噻咯二酚类化合物、合成方法及其应用, 专利申请号:CN 202010117280.X
4. 王鹏, 常鑫; 螺双二氢苯并噻咯亚磷酰胺类化合物、其制备方法及应用, 专利申请号:CN 202010117722.0
3. 王鹏, 陈小月, 聂晓雪, 吴奕晨; 对位取代芳基化合物的制备方法, 专利申请号:CN 202010063307.1
2. 王鹏, 余锦锋, 李健军; 一种通过铜催化剂介导的杂环-杂环C-N交叉脱氢偶联反应方法。专利申请号:CN 201910381730.3
1. 王鹏, 李健军, 王成钢, 余锦锋; 一种通过铜催化的sp2杂化碳氢键的烯基化反应方法, 专利申请号:CN 201910866561.2