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44. Luo, Y.; Huang, G.; Ding, K.*; Xue, X.-S.*; Wang, X.* Nat. Chem. 2025, 17, 1196-1206. Oxygen transposition of formamide to α-aminoketone moiety in a carbene-initiated domino reaction.

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41. Xu, J.; Wang, G.; Ding, K.; Wang, X.* J. Am. Chem. Soc. 2025, 147, 2000-2009, Dirhodium-Palladium Dual-Catalyzed [1 + 1 + 3] Annulation to Heterocycles Using Primary Amines or H2O as the Heteroatom Sources.

40. Xu, G.; Chen, H.; Wang, X.*, Science China Chemistry. 2025, 68, 3138-3146. Enantioselective β-Alkenylation of α,β-Unsaturated Aldehydes via Chiral Biphosphine Ligand Modified Dirhodium(II) Catalysis.

39. Liu, Y.#; Chen, H.#; Wang, X.* J. Am. Chem. Soc. 2024, 146, 28427-28436. Synergistic Homogeneous Asymmetric Cu Catalysis with Pd Nanoparticle Catalysis in Stereoselective Coupling of Alkynes with Aldimine Esters.

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37. Wang, Y.; Li, S. -J.; Jiang, F.; Lan, Y.*; Wang, X.*, J. Am. Chem. Soc. 2024, 146, 19286–19294. Making Full Use of TMSCF3: Deoxygenative Trifluoromethylation/Silylation of Amides.

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32. Chen, K#.; Zhu, H#.; Li, S.; Bai, J.; Guo, Y.; Ding, K.*; Peng, Q.*; Wang, X.*, J. Am. Chem. Soc. 2023, 145, 24877–24888. Switch in Selectivities by Dinuclear Nickel Catalysis: 1,4-Hydroarylation of 1,3-Dienes to Z-Olefins.

31. Li, J.; He, Y.; Jiang, F.*; Wang, X.*, Green Chem. 2023, 25, 9080-9085. Deoxygenative Arylation of Secondary Amides by Merging Iridium Catalysis with Electrochemical Radical Cross-coupling.

30. Cai, Q.; Rao, H.; Li, S. -J.; Lan, Y.*; Ding, K.*; Wang, X.*, Chem 2024, 10, 265-282. Well-defined chiral dinuclear copper complexes in enantioselective propargylic substitution: For a long-standing supposition on binuclear mechanism.

29. Yao, J.; Shao, L.; Huo, X.*; Wang, X.*, Sci. China Chem. 2023, 67, 882-889. Synergistic Silver-mediated and Palladium-catalyzed Nondirected Olefination of Aryl C–H Bond: Quick Access to Multi-substituted Aryl Olefins.

28. Xu, J.; Ge, Z.; Ding, K.; Wang, X.*, JACS Au, 2023, 3, 2862–2872. Rh(II)/Pd(0) Dual-Catalyzed Regio-Divergent Three-Component Propargylic Substitution.

27. Zhao, C; Ge, Z.; Hu, J.; Tian, H.; Wang, X.*, Cell Rep. Phys. Sci. 2023, 4, 101474. Enantioselective reductive aryl-benzylation of alkenes by a nickel-titanium bimetallic system.

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24. Jiang, F.; Li, J.; Wang, X.*, Chem. Eur. J. 2023, e202301199. Deoxygenative Radical Boration of Inert Amides via a Combination of Relay and Cooperative Catalysis.

23. Tian, H.; Zhang, R.; Shi, L.; Zhao, C.*; Wang, X.*, Chin. J. Chem. 2023, 41, 1783-1790. Divergent Synthesis of Organofluorinated Molecules from Titanium Mediated Deoxygenation of Free Alcohols.

22. Liu, S.; Zou, L.*; Wang, X.*, Chin. J. Org. Chem. 2023, 43, 1713-1725. The Advance of Dehydrogenation and Transfer Hydrogenation of Ammonia-Borane Catalyzed by Homogeneous Cobalt Complexes.

21. Yang, W.; Jiao, J.; Wang, X.*, Chin. J. Org. Chem. 2023, 43, 1857-1867. Merging Electron Transfer Activation with 1,2-Metalate Migration: Deoxygenative Silylation of Amides.

20. Yao, J.; Bai, J.; Kang, X.; Zhu, M.; Guo, Y.*; Wang, X.*, Nanoscale 2023, 15, 3560-3565. Non-directed C–H arylation of electron-deficient arenes by synergistic silver and Pd3 cluster catalysis.

19. Ge, Z.; Lu, B.; Teng H.*; Wang, X.*, Chem. Eur. J. 2023, 29, e202202820. Efficient Synthesis of Diaryl Quaternary Centers by Rh(II)/Xantphos Catalyzed Relay C-H Functionalization and AllylicAlkylation. (Highlighted by Synfacts 2023, 19, 0038)

18. Jiao, J.; Yang W.; Wang, X.*, J. Org. Chem. 2023, 88, 594–601. α-Aminocarbene-Mediated Si–H Insertion: Deoxygenative Silylation of Aromatic Amides with Silanes.

17. Zhang, J.#; Lu, B.#; Ge, Z.; Wang, L.*; Wang, X.*, Org. Lett. 2022, 24, 8423–8428. Selective Construction of All-Carbon Quaternary Centers via Relay Catalysis of Indole C-H Functionalization/Allylic Alkylation. (#contributed equally to this work)

16. Wang, Y.; Shao, Y.; Xue, X.*; Wang, X.*, Cell Rep. Phys. Sci. 2022, 3, 101116. Incorporation of Germanium into Amines via Deoxygenative Germylation of Aromatic Amides with Hydrogermanes.

15. Li, F.; Lu, B.; Liu, Y.*; Wang, X.*, Chin. J. Org. Chem. 2022, 42, 3390–3397. Dirhodium/Xantphos-Catalyzed Tandem C-H Functionalization/Allylic Alkylation: Direct Access to 3-Acyl-3-Allyl Oxindoles Derivatives from N-Aryl-α-Diazo-β-Keto Amides.

14. Zhao, F.#; Jiang, F.#; Wang, X.*, Sci. China Chem. 2022, 65, 2231–2237. Deoxygenative Alkylation of Tertiary Amides Using Alkyl Iodides under Visible Light(#contributed equally to this work). (Included in 2022 Emerging Investigator Issue of Science China Chemistry)

13. Liu, T.#; Li, C.#; Bai, J.; Zhang, P.*; Guo, Y.*; Wang,X.*, Chin. J. Chem. 2022, 40, 2203-2211. Markovnikov-Selective Hydroboration of Aryl Alkenes Enabled by a Simple Nickel Salt (#contributed equally to this work).

12. Jiang, F.#; Zhao, F.#; He Y.; Luo, X.; Wang, X.*, Cell Rep. Phys. Sci. 2022, 3, 100955. Efficient Synthesis of β-Substituted Amines via Combining Deoxygenation of Amides with Photochemical Organocatalysis (#contributed equally to this work).

11. Zhang, J.#; Liu, T.#; Wang, L.*; Wang, X.*, Chin. J. Org. Chem. 2022, 42, 2331-2341. Recent Process in the in situ Generated Metal Nanocluster Catalysis (#contributed equally to this work, review, in Chinese).

10. Yang, Y.#; Lu, B.#; Xu,G.*; Wang, X.*, ACS Cent. Sci. 2022, 8, 581-589. Overcoming O-H Insertion to Para-Selective C-H Functionalization of Free Phenols: Rh(II)/Xantphos Catalyzed Geminal Difunctionalization of Diazo Compounds (#contributed equally to this work).

9. He, Y.; Wang, Y.; Li, S. J.; Lan, Y.*; Wang, X.*, Angew.Chem. Int. Ed. 2022, e202115497. Deoxygenative Cross-Coupling of Aromatic Amides with Polyfluoroarenes.

8. Ma, S.; Li, F.; Zhang, G.*; Shi, L.*; Wang, X.*, ACS Catal. 2021, 11, 14848-14853. Highly Regioselective Difluoroalkylarylationof Butadiene through a Nickel-Catalyzed Tandem Radical Process.

7. Chen, K.#; Zhu, H.#; Li, Y.; Peng, Q.*; Guo, Y.*; Wang, X.*, ACS Catal. 2021, 11, 13696-13705. Dinuclear Cobalt Complex-Catalyzed Stereodivergent Semireduction of Alkynes: Switchable Selectivities Controlled by H2O. (#contributed equally to this work).

6. Li, Z.; Zhao, F.; Ou, W.; Huang, P. -Q.*; Wang, X.*, Angew. Chem. Int. Ed. 2021, 60, 26604-26609. Asymmetric Deoxygenative Alkynylation of Tertiary Amides Enabled by Iridium/Copper Bimetallic Relay Catalysis.

5. Song, S.; Li, C.; Liu, T.; Zhang, P.*; Wang, X.*, Org. Lett. 2021, 23, 6925-6930. H-BPin/KOtBu Promoted Activation of Cobalt Salt to a Heterotopic Catalystfor Highly Selective Cyclotrimerization of Alkynes.

4. Lu, B.; Liang, X.; Zhang, J.; Wang, Z.; Peng, Q.*; Wang, X.*, J. Am. Chem. Soc. 2021, 143, 11799-11810. Dirhodium(II)/Xantphos-Catalyzed Relay Carbene Insertion and Allylic Alkylation Process: Reaction Development and Mechanistic Insights.

3. Li, C.; Song, S.; Li, Y.; Xu, C.; Luo, Q.; Guo, Y.*; Wang, X.*, Nat. Commun. 2021, 12, 3813-3820. Selective hydroboration of unsaturated bonds by an easily accessible heterotopic cobalt catalyst.

2. Jiao, J.; Wang, X.*, Angew. Chem. Int. Ed. 2021, 60, 17088-17093. Merging Electron Transfer with 1,2-Metalate Rearrangement: Deoxygenative Arylation of Aromatic Amides with Arylboronic Esters.

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Supervised Work (Before 2019)
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9. Wang, X.; Nozaki, K.*, J. Am. Chem. Soc. 2018, 140, 15635-15640. Selective Chain-End Functionalization of Polar Polyethylenes: Orthogonal Reactivity of Carbene and Polar Vinyl Monomers in Their Copolymerization with Ethylene.
8. Wang, X.#; Li; Y,.#; Daniliuc, C. G.; Houk; K. N.*; Glorius, F.*, Angew. Chem. Int. Ed. 2018, 57, 5520-5524. Unprecedented Dearomatized Spirocyclopropane in a Sequential Rh(III)-catalyzed C-H Activation and Rearrangement Reaction. (#Both authors contributed equally.)
7. Wang, X.; Lerchen, A.; Daniliuc, C. G.; Glorius, F.*, Angew. Chem. Int. Ed. 2018, 57, 1712-1716. Efficient Synthesis of Arylated Furans Enabled by a Sequential Rh-catalyzed Arylation and Cycloisomerization of Cyclopropenes.
6. Wang, X.; Gensch, T.; Lerchen, A.; Daniliuc, C. G.; Glorius, F.*, J. Am. Chem. Soc. 2017, 139, 6506-6512. Cp*Rh(III)/Bicyclic Olefin Cocatalyzed C-H Bond Amidation by Intramolecular Amide Transfer. (Top 20 most read JACS papers in May, 2017. Highlighted by Chemistry Views.)
5. Wang, X.; Lerchen, A.; Gensch, T.; Knecht, T.; Daniliuc, C. G.; Glorius, F.*, Angew. Chem. Int. Ed. 2017, 56, 1381-1384. Combination of Cp*RhIII-Catalyzed C-H Activation and a Wagner-Meerwein-Type Rearrangement.
4. Wang, X.#; Yu, D. -G.#; Glorius, F.*, Angew. Chem. Int. Ed. 2015, 54, 10280. Cp*RhIII-Catalyzed Arylation of C(sp3)-H Bonds. (#Both authors contributed equally.)
3. Wang, X.; Guo, P.; Han, Z.; Wang, X.; Wang, Z.; Ding, K.*, J. Am. Chem. Soc. 2014,136, 405-411. Spiroketal-Based Diphosphine Ligands in Pd-Catalyzed Asymmetric Allylic Amination of Morita-Baylis-Hillman Adducts: Exceptionally High Efficiency and New Mechanism.
2. Wang, X.; Meng, F.; Wang, Y.; Han, Z.; Chen, Y. -J.; Liu, L.*; Wang, Z.*; Ding, K.*, Angew. Chem. Int. Ed. 2012, 51, 9276-9282. Aromatic Spiroketal Bisphosphine Ligands: Palladium-Catalyzed Asymmetric Allylic Amination of Racemic Morita–Baylis–Hillman Adducts. (Highlighted by SYNFACTS, 2012, 1286).
1. Wang, X.; Han, Z.; Wang, Z.*; Ding, K.*, Angew. Chem. Int. Ed. 2012, 51, 936-940. Catalytic Asymmetric Synthesis of Aromatic Spiroketals by SpinPhox/Iridium(I)-Catalyzed Hydrogenation and Spiroketalization of α,α’-Bis(2-hydroxyarylidene)-Ketones. (Highlighted by Angew. Chem. Int. Ed. 2012, 51, 9486-9488 and SYNFACTS, 2012, 412).