烯烃配位聚合

可循环聚烯烃

过渡金属催化的高选择性反应

1.          Jialong Zhang,# Alexander H. Mason,# Yang Wang, Alessandro Motta, Takeshi Kobayashi, Marek Pruski, Yanshan Gao* and Tobin J. Marks.* Beyond the Active Site. Cp*ZrMe3/Sulfated Alumina-Catalyzed Olefin Polymerization Tacticity via Catalyst···Surface Ion-Pairing. ChemCatChem. 2021, Just Accepted, DOI: 10.1002/cctc.202100406.

2.          Jialong Zhang,# Alexander H. Mason,# Alessandro Motta,* Laryssa G. Cesar, Yosi Kratish, Tracy L. Lohr, Jeffery T. Miller,* Yanshan Gao* and Tobin J. Marks.* Surface vs Homogeneous Organo-Hafnium Catalyst Ion-Pairing and Ligand Effects on Ethylene Homo- and Copolymerizations. ACS Catal. 2021, 11, 3239–3250.

3.          Cole Carter, Yosi Kratish, Titel Jurca, Yanshan Gao* and Tobin J. Marks.* Bis-Ferrocenyl-Pyridinediimine Trinuclear Mixed-Valent Complexes with Metal-Binding Dependent Electronic Coupling: Synthesis, Structures, and Redox-Spectroscopic Characterization. J. Am. Chem. Soc. 2020, 142, 18715–18729.

4.          Yosi Kratish, Jiaqi Li, Shanfu Liu, Yanshan Gao* and Tobin J. Marks.* Polyethylene Terephthalate Deconstruction Catalyzed by a Carbon-Supported Single-Site Molybdenum-Dioxo Complex. Angew. Chem. Int. Ed. 2020, 59, 19857-19861.

5.          Minglu Huang, Jiazhen Chen, Binghao Wang, Wei Huang, Haibo Chen, Yanshan Gao* and Tobin J. Marks.* Polar Isotactic and Syndiotactic Polypropylenes via Organo-zirconium-Catalyzed Masking-Reagent-Free Propylene + Amino-Olefin Copolymerizations. Angew. Chem. Int. Ed. 2020, 59, 20522 – 20528.

6.          Jiazhen Chen, Yanshan Gao* and Tobin J. Marks.* Early Transition Metal Catalysis for Olefin-Polar Monomer Copolymerization. Angew. Chem. Int. Ed. 2020, 59, 14726-14735.

7.          Yanshan Gao* and Tobin J. Marks.* Versatile catalytic strategy for polar-functionalized, cross-linkable, self-healing, and photo-responsive polyolefins. Science Bulletin 2020, 65, 605–606.

8.          Jiazhen Chen,# Alessandro Motta,#* Jialong Zhang, Yanshan Gao,* and Tobin J. Marks.* Mechanism of Organoscandium-Catalyzed Ethylene Copolymerization with Amino-Olefins: A Quantum Chemical Analysis. ACS Catal. 2019, 9, 8810-8818.

9.          Yanshan Gao, Matthew Christianson, Yang Wang, Jiazhen Chen, Steve Marshall, Jerzy Klosin,* Tracy L. Lohr,* and Tobin J. Marks.* Unexpected Precatalyst σ-Ligand Effects in Phenoxyimine Zr-Catalyzed Ethylene/1-Octene Copolymerizations. J. Am. Chem. Soc. 2019, 141, 7822-7830.

10.       Jiazhen Chen, Alessandro Motta, Binghao Wang, Yanshan Gao,* and Tobin J. Marks.* Significant Polar Comonomer Enchainment in Zr-Catalyzed, Masking Reagent-Free, Ethylene Copolymerizations. Angew. Chem. Int. Ed. 2019, 131, 7104-7108.

11.       Yanshan Gao, Jiazhen Chen, Yang Wang, David Pickens, Alessandro Motta, Q. Jane Wang, Yip-Wah Chung, Tracy Lohr* and Tobin J. Marks.* Highly Branched Polyethylene Oligomers via Single-Site Polymerization in Very Nonpolar Media. Nature Catalysis, 2019, 2, 236-242. Front Cover, March 2019; “News &Views” report.

12.       Yanshan Gao, Xia Chen, Jialong Zhang, Jiazhen Chen, Tracy L. Lohr,* and Tobin J. Marks.* Catalyst Nuclearity Effects on Stereo- and Regio-induction in Pyridylamidohafnium-Catalyzed Propylene and 1-Octene Polymerizations. Macromolecules, 2018, 51, 2401-2410.

13.       Yanshan Gao, Aidan R. Mouat, Alessandro Motta, Alceo Macchioni,* Cristiano Zuccaccia,* Massimiliano Delferro,* and Tobin J. Marks.* Pyridylamido bi-Hafnium Olefin Polymerization Catalysis: Conformationally Supported Hf···Hf Enchainment Cooperativity. ACS Catal. 2015, 5, 5272-5282.

14.       Wei Huang, Po-Hsiu Chien, Kyle McMillen, Joshua Tedesco, Li Zeng, Subhrangsu Mukherjee, Binghao Wang, Yao Chen, Gang Wang, Yang Wang, Yanshan Gao, Michael J. Bedzyk,* Dean DeLongchamp,* Yan-Yan Hu,* Julia E. Medvedeva,* Tobin J. Marks,* Antonio Facchetti.* Polymers as Oxide Semiconductor Dopants. Experimental and Theoretical Evidence for Hydrogen Doping in Solution-Processed Indium Gallium Oxide. PNAS, 2020, 117, 18231-18239.

15.       Jialong Zhang, Alessandro Motta, Yanshan Gao, Madelyn Marie Stalzer, Massimiliano Delferro, Boping Liu, Tracy L. Lohr* and Tobin J. Marks.* Cationic Pyridylamido Adsorbate on Bronsted Acidic Sulfated Zirconia: A Molecular Supported Organohafnium Catalyst for Olefin Homo- and Co-Polymerization. ACS Catal. 2018, 8, 4893-4901.

16.       Jiazhen Chen, Yanshan Gao, Binghao Wang, Tracy L. Lohr,* and Tobin J. Marks.* Scandium-Catalyzed Self-Assisted Polar Comonomer Enchainment in Ethylene Polymerization. Angew. Chem. Int. Ed. 2017, 56, 15964-15968.

17.       Jiazhen Chen, Yanshan Gao, Shuoyan Xiong, Massimiliano Delferro, Tracy L. Lohr,* and Tobin J. Marks.* Metal and Counteranion Nuclearity Effects in Organoscandium-Catalyzed Isoprene Polymerization and Copolymerization. ACS Catal. 2017, 7, 5214-5219.

18.       Dawei Wan, Zhou Chen, Yanshan Gao, Qi Shen, Xiuli Sun,* Yong Tang. Synthesis and Characterization of Tridentate [O-N(H)X] Titanium Complexes and Their Applications in Olefin Polymerization. J. Polym. Sci. Polym. Chem. 2013, 51, 2495-2503.

19.       Dawei Wan, Yanshan Gao, Junfang Li, Qi Shen, Xiuli Sun* and Yong Tang. Synthesis, Structure, and Ethylene Polymerization Behavior of Nickel Complexes Based on Benzoylmethylenetri(2-alkoxylphenyl)phosphorane. Dalton Trans., 2012, 41, 4552-4557.