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姓 名: |
张雪 |
性 别: |
女 |
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职 称: |
副研究员 |
学 历: |
博士研究生 |
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电 话: |
021-54925154 |
传 真: |
021-64166128 |
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电子邮件: |
xzhang@sioc.ac.cn |
个人主页: |
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通讯地址: |
上海市零陵路345号 200032 |
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| 简历： |
教育背景：
2002年9月至2007年7月：中科院上海有机所金属有机重点实验室攻读博士学位，专业为理论有机化学，导师为丁奎岭研究员
1998年9月至2002年7月：南开大学化学学院获得学士学位
工作经历：
2011年3月至今：中科院上海有机化学研究所金属有机化学国家重点实验室麻生明组副研究员
2009年1月2011年2月：美国北德克萨斯大学（University of North Texas）Professor Weston T. Borden 研究组从事博士后研究
2007年7月至2008年12月：中科院上海有机所金属有机重点实验室丁奎岭课题组，助理研究员 |
| 研究方向： |
运用电子结构理论研究不同类型分子体系的化学反应机理 |
| 代表论著： |
1.Xue Zhang, Ayan Datta, David A. Hrovat, and Weston Thatcher Borden*, “Calculations Predict Large Inverse Kinetic Isotope Effects on Tunneling by Carbon in the Ring Opening of Cyclopropylcarbinyl Radical at Cryogenic Temperatures”, J. Am. Chem. Soc. 2009, 131, 16002-16003.
2.Xue Zhang, David A. Hrovat, and Weston Thatcher Borden*, “Calculations Predict That Carbon Tunneling Allows the Degenerate Cope Rearrangement of Semibullvalene to Occur Rapidly at Cryogenic Temperatures”, Org. Lett. 2010, 12, 2798-2801.
3.Xue Zhang, Srikanth Kandala, Li Yang, William H. Watson, Xiaoping Wang, David A. Hrovat, Weston Thatcher Borden,* and Michael G. Richmond*, “Experimental and Computational Studies of the Isomerization Reactions of Bidentate Phospine Ligands in Triosmium Clusters: Kinetics of the Rearrangements from Bridged to Chelated Isomers and X-ray Structures of the Clusters Os3(CO)10(dppbz), 1,1-Os3(CO)10(dppbzF4), HOs3(CO)9[μ-1,2-PhP (C6H4-η1)C6H4PPh2], and HOs3(CO)9[μ-1,2-PhP(C6H4-η1)C6F4PPh2]”, Organometallics 2011, 30, 1253–1268.
4.Xue Zhang, David A. Hrovat, Ayan Datta and Weston Thatcher Borden*, “Effects of Geminal Methyl Groups on the Tunnelling Rates in the Ring Opening of Cyclopropylcarbinyl Radical at Cryogenic Temperature”, Organic & Biomolecular Chemistry ASAP.
5.Xue Zhang, Haifeng Du, Zheng Wang, Yun-Dong Wu,* and Kuiling Ding*, “Experimental and Theoretical Studies on the Hydrogen-Bond-Promoted Enantioselective Hetero-Diels-Alder Reaction of Danishefsky’s Diene with Benzaldehyde”, J. Org. Chem. 2006, 71, 2862-2869.
6.Ollie M. Gonzalez-James, Xue Zhang, Ayan Datta, David A. Hrovat, Weston Thatcher Borden*, and Daniel A. Singleton*, “Experimental Evidence for Heavy-Atom Tunneling in the Ring-Opening of Cyclopropylcarbinyl Radical from Intramolecular 12C/13C Kinetic Isotope Effects”, J. Am. Chem. Soc. 2010, 132, 12548-12549.
7.Liu, Y.; Sandoval, C. A.; Yamaguchi, Y.; Zhang, X.; Wang, Z.; Kato, K.; Ding, K*., “Hydrogen Bonding Makes a Difference in the Rhodium-Catalyzed Enantioselective Hydrogenation Using Monodentate Phosphoramidites”, J. Am. Chem. Soc., 2006; 128, 14212-14213.
8.Qing Jing, Xue Zhang, Jie Sun, Kuiling Ding*, “Bulky Achiral Triarylphosphines Mimic BINAP in Ru(II)-Catalyzed Asymmetric Hydrogenation of Ketones”, Adv. Synth. Catal. 2005, 347, 1193–1197.
9.Haifeng Du, Xue Zhang, Zheng Wang, and Kuiling Ding*, “One catalyst for two distinct reactions: sequential asymmetric hetero Diels-Alder reaction and diethylzinc”, Tetrahedron, 2005, 40, 9465-9477.
10.Wen, YQ; Song, YL; Zhao, DB; Ding, KL; Bian, J; Zhang, X; Wang, JX; Liu, Y; Jiang, L; Zhu, DB, “Highly regio- and enantioselective thermal [2+2] cycloaddition of coumarin in a crystalline inclusion complex under high vacuum”, Chem. Commun. 2005, 21, 2732-2734.
11.Yu Yuan, Xue Zhang, and Kuiling Ding*, “Quasi solvent-free enantioselective carbonyl-ene reaction with extremely low catalyst loading”, Angew. Chem. Int. Ed. 2003, 42, 5478 –5480. |
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