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2024

148
 Copper-Catalyzed sp2 C-H Arylation and Alkynylation of Allenes via Hydrogen Atom Abstraction
Zhongming Cheng,# Jiajun Zhang,# Can Li, Xiang Li, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2024, 146, 24689-24698.
147
Asymmetric 1,n-Remote Aminoacetoxylation of Unactivated Internal Alkenes Enabled by Palladium Catalysis
Xintuo Yang, Pinhong Chen, Guosheng Liu* Angew. Chem. Int. Ed. 2024, 63, e202408305
146
Palladium-Catalyzed Remote Hydrosulfonamidation of Alkenes: Access to Primary N-Alkyl Sulfamides by the SuFEx Reaction
Chuanqi Hou,# Zhenye Liu,# Lan Gan, Wenzheng Fan, Lin Huang, Pinhong Chen, Zheng Huang, Guosheng Liu* J. Am. Chem. Soc. 2024, 146, 13536–13545.
145
Palladium(II)-Catalyzed Markovnikov Hydroalkynylation of Unactivated Terminal Alkenes. 
Chuanqi Hou, Pinhong Chen,* Guosheng Liu* Chin. J. Chem. 2024, 42, 29–34.

2023

144
  Site-selective sp2 C-H Cyanation of Allenes via Copper-catalyzed Radical Relay.
Zhongming Cheng, Tilong Yang, Can Li, Yunshun Deng, Fangjia Zhang, Pinhong Chen, Zhenyang Lin,* Shengming Ma,* Guosheng Liu* J. Am. Chem. Soc. 2023, 145, 25995–26002.
143
  Cu/photoredox-catalyzed decarboxylative radical C(sp3)–C(sp3) cross-coupling reactions
Chao Jiang, Pinhong Chen, Guosheng Liu* Sci. China Chem. 2023, 66, 2858–2862.
142
  Palladium-catalyzed Asymmetric Oxycarbonylation of Internal Z-Alkenes.
Changyu Shao, Chuanqi Hou, Pinhong Chen, Haihui Peng,* Guosheng Liu* Asian J. Org. Chem. 2023, 12, e20230016.
141
Copper-Catalyzed Asymmetric Functionalization of Vinyl Radicals for the Access to Vinylarene Atropisomers.
Liang Fu,# Xin Chen,# Wenzheng Fan, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2023,145,13476–13483.
140
Regio- and enantioselective remote dioxygenation of internal alkenes.
Xiaonan Li, Tilong Yang, Jiaoyuan Li, Xiang Li, Pinhong Chen, Zhenyang Lin*, Guosheng Liu* Nat. Chem. 2023, 15, 862–871.
139
Asymmetric Palladium-Catalyzed Aminochlorination of Unactivated Alkenes.
Zhigang Wang, Chuanqi Hou, Pinhong Chen* Org. Lett. 2023, 25, 2685–2690.
138
 Enantioselective Cyanation of Propargylic C-H Bonds via Cooperative Photoredox and Copper Catalysis.
Yunshun Deng, # Ronghua Lu, # Pinhong Chen,* Guosheng Liu* Chem. Commun. 2023, 59, 4656-4659.

2022

137
 Asymmetric Palladium-Catalyzed Aza-Wacker Reaction of Alkenes: Efficient Synthesis of Chiral 1,3-Oxazinan-2-ones.
Xintuo Yang, Pinhong Chen, Guosheng Liu* Chin. J. Org. Chem. 2022, 42, 3382–3389.
136
 Palladium-Catalyzed Remote Hydrooxygenation of Internal Alkenes: An Efficient Access to Primary Alcohols.
Xiang Li, Xintuo Yang, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2022, 144, 22877–22883.
135
 Electrophotocatalytic Decoupled Radical Relay Enables Highly Efficient and Enantioselective Benzylic C–H Functionalization.
Wenzheng Fan#, Xueyao Zhao#, Yunshun Deng, Pinhong Chen, Fei Wang,* Guosheng Liu* J. Am. Chem. Soc. 2022, 144, 21674–21682.
134
Enantioselective Radical Trifluoromethylation of Benzylic C–H Bonds via Cooperative Photoredox and Copper Catalysis.
Pin Xu, Wenzheng Fan, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2022, 144, 13468–13474.
133
Asymmetric Alkynylation of Tertiary Carbon-Centered Radical via Copper-Catalyzed Radical Relay
Dunqi Wu, Lianqian Wu, Pinhong Chen, Guosheng Liu* Chin. J. Chem. 2022, 40, 1699–1704.
132
Palladium(II)-Catalyzed Enantioselective Hydrooxygenation of Unactivated Terminal Alkenes
Xintuo Yang, Xiang Li, Pinhong Chen*, Guosheng Liu* J. Am. Chem. Soc. 2022, 144, 7972–7977.
131
Copper-Catalyzed Enantioselective Radical Chlorination of Alkenes.
Dunqi Wu, Wenzheng Fan, Lianqian Wu, Pinhong Chen, Guosheng Liu* ACS Catal. 2022, 12, 5284–5291.
130
Palladium-Catalyzed Intermolecular Carbonylation-Based Difunctionalization of Alkenes.
Bing Tian, Pinhong Chen, Guosheng Liu* Synlett 2022, 33, 927–938.
129
Palladium-catalyzed intermolecular alkynylcarbonylation of unactivated alkenes: an easy access to β-alkynylcarboxylic esters.
Xiang Li, Pinhong Chen,* Guosheng Liu* Chem. Commun. 2022, 58, 2544-2547.
128
Copper-catalyzed radical relay in C(sp3)–H functionalization.
Zuxiao Zhang, Pinhong Chen, Guosheng Liu* Chem. Soc. Rev. 2022, 51, 1640-1658.
127
Catalytic remote hydrohalogenation of internal alkenes.

Xiang Li,# Jianbo Jin,# Pinhong Chen, Guosheng Liu* Nat. Chem. 2022, 14, 425–432.
126
Copper-catalysed asymmetric radical cyanation.

Fei Wang, Pinhong Chen, Guosheng Liu* Nat. Synth. 2022, 1, 107–116.

2021

125
Enantioselective Copper-Catalyzed Radical Cyanation of Propargylic C–H Bonds: Easy Access to Chiral Allenyl Nitriles.
Ronghua Lu#, Tilong Yang#, Xin Chen, Wenzheng Fan, Pinhong Chen, Zhenyang Lin,* Guosheng Liu* J. J. Am. Chem. Soc. 2021, 143, 14451–14457.
124
Asymmetric Palladium-Catalyzed Oxycarbonylation of Terminal Alkenes: Efficient Access to β-Hydroxy Alkylcarboxylic Acids.
Bing Tian, Xiang Li, Pinhong Chen, Guosheng Liu* Angew. Chem. Int. Ed. 2021, 60, 14881–14886.
123
Anionic Bisoxazoline Ligands Enable Copper-Catalyzed Asymmetric Radical Azidation of Acrylamides.
Lianqian Wu,# Zhihan Zhang,# Dunqi Wu,# Fei Wang, Pinhong Chen, Zhenyang Lin,* Guosheng Liu* Angew. Chem. Int. Ed. 2021, 60, 6997 –7001.
122
Palladium-Catalysed Enantioselective Diacetoxylation of Terminal Alkenes.
Bing Tian, Pinhong Chen , Xuebing Leng, Guosheng Liu* Nat. Catal. 2021, 4, 172-179.
121
Enantioselective Intermolecular Aminoalkynylation of Styrenes via Copper-Catalyzed Radical Relay.
Zhoumi Hu, Liang Fu, Pinhong Chen, Weiguo Cao,* Guosheng Liu* Org. Lett. 2021, 23, 129–134.
120
Enantioselective Arylcyanation of Styrenes via Copper-Catalyzed Radical Relay.
Weiwen Zhuang, Pinhong Chen, Guosheng Liu* Chin. J. Chem. 2021, 39, 50?54.

2020

119
Ligand-Controlled Regioselective Pd-Catalyzed Diamination of Alkenes.
Xiaojian Liu, Chuanqi Hou, Yiyuan Peng,* Pinhong Chen,* Guosheng Liu* Org. Lett. 2020, 22, 9371?9375.
118
Copper-Catalyzed Benzylic C–H Bond Thiocyanation: Enabling Late-Stage Diversifications.
Chao Jiang, Pinhong Chen, Guosheng Liu* CCS Chemistry 2020, 2, 1884–1893.
117
Enantioselective Copper-Catalyzed Trifluoromethylation of Benzylic Radicals via Ring Opening of Cyclopropanols
Chao Jiang, Lei Wang, Honggang Zhang, Pinhong Chen, Yin-Long Guo, Guosheng Liu* Chem. 2020, 6, 2407-2419.
116
Asymmetric Coupling of Carbon-Centered Radical Adjacent to Nitrogen: Copper-Catalyzed Cyanation and Etherification of Enamides.
Guoyu Zhang, Song Zhou, Liang Fu, Pinhong Chen, Yibiao Li,* Jianping Zou,* Guosheng Liu* Angew. Chem. Int. Ed. 2020, 59, 20439-20444.
115
Palladium(II)-Catalyzed Enantioselective Azidation of Unactivated Alkenes.
Xiaonan Li, Xiaoxu Qi, Chuanqi Hou, Pinhong Chen,* Guosheng Liu* Angew. Chem. Int. Ed. 2020, 59, 17239-17244.
114
Copper-Catalyzed Asymmetric Cyanation of Alkenes via Carbonyl-Assisted Coupling of Alkyl-Substituted Carbon-Centered Radicals.
Song Zhou, Guoyu Zhang, Liang Fu, Pinhong Chen, Yibiao Li,* Guosheng Liu* Org. Lett. 2020, 22, 6299–6303.
113
Enantioselective Copper-Catalyzed Alkynylation of Benzylic C-H Bonds via Radical Relay.
Liang Fu, Zhihan Zhang, Pinhong Chen, Zhenyang Lin*, Guosheng Liu* J. Am. Chem. Soc. 2020, 142, 12493–12500.
112
Palladium(II)-Catalyzed Aminotrifluoromethoxylation of Alkenes: Mechanistic Insight into the Effect of N-Protecting Groups.
Chaohuang Chen, Chuanqi Hou, Pinhong Chen, Guosheng Liu* Chin. J. Chem. 2020, 38, 346–350.
111
Enantioselective Copper-Catalyzed Radical Ring-Opening Cyanation of Cyclopropanols and Cyclopropanone Acetals.
Lianqian Wu, Lei Wang, Pinhong Chen, Yin-Long Guo,* GuoshengLiu* Adv. Synth. Catal. 2020, 362, 2189-2194.
110
Enantioselective Palladium(II)-Catalyzed Oxidative Aminofluorination of Unactivated Alkenes with Et4NF·3HF as a Fluoride Source.
Chuanqi Hou, Pinhong Chen, Guosheng Liu* Angew. Chem. Int. Ed. 2020, 59, 2735-2739.
109
Recent Advances and Perspectives in Transition Metal-Catalyzed 1,4-Functionalizations of Unactivated 1,3-Enynes for the Synthesis of Allenes.
Liang Fu, Steffen Gre?ies, Pinhong Chen, Guosheng Liu* Chin. J. Chem. 2020, 38, 91-100.

2019

108
Site-specific Allylic C-H Bond Functionalization with a Copper-Bound N-Centred Radical.
Jiayuan Li, Zhihan Zhang, Lianqian Wu, Wen Zhang, Pinhong Chen, Zhenyang Lin,* Guosheng Liu* Nature 2019, 574, 516–521.
107
Iodine(III) reagent (ABX—N3)-induced intermolecular anti-Markovnikov hydroazidation of unactivated alkenes.
Xiaonan Li, Pinhong Chen, Guosheng Liu* Sci. China Chem. 2019, 62, 1537-1541.
106
Enantioselective Cyanation of Remote C-H Bonds via Cooperative Photoredox Catalysis and Copper Catalysis. (cover paper)
Zhongming Cheng; Pinhong Chen; Guosheng Liu* Acta Chim. Sinica 2019, 77, 856-860.
105
Proton-Coupled Electron Transfer Enables Tandem Radical Relay for Asymmetric Copper-Catalyzed Phosphinoylcyanation of Styrenes.
Guoyu Zhang, Liang Fu, Pinhong Chen, Jianping Zou*, Guosheng Liu* Org. Lett. 2019, 21, 5015-5020.
104
Enantioselective Arylation of Benzylic C-H bonds via CopperCatalyzed Radical Relay.
Wen Zhang, Lianqian Wu, Pinhong Chen, Guosheng Liu* Angew. Chem. Int. Ed. 2019, 58, 6425-6429.
103
Palladium(II)-Catalyzed Enantioselective Aminotrifluoromethoxylation of Unactivated Alkenes using CsOCF3 as a Trifluoromethoxide Source.
Chaohuang Chen, Philipp Miro Pflüger, Pinhong Chen, Guosheng Liu* Angew. Chem. Int. Ed. 2019, 58, 2392 –2396.
102
Enantioselective Construction of Quaternary All-Carbon Centers via Copper-Catalyzed Arylation of Tertiary Carbon-Centered Radicals.
Lianqian Wu, Fei Wang, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2019, 141, 1887?1892.
101
Palladium-Catalyzed Intramolecular Fluoroarylation of Alkenes.
Wencheng Yang, Xiaoxu Qi, Pinhong Chen,* Guosheng Liu* Chin. J. Org. Chem. 2019, 39, 122-128.

2018

100
Pd-Catalyzed Intermolecular Arylcarbonylation of Unactivated Alkenes: Incorporation of Bulky Aryls at Room Temperature.
Xiang Li, Pinhong Chen*, Guosheng Liu* Angew. Chem. Int. Ed. 2018, 57, 15871–15876.
99
Copper-Catalyzed Radical Relay for Asymmetric Radical Transformations.
Fei Wang, Pinhong Chen, Guosheng Liu* Acc. Chem. Res. 2018, 51, 2036–2046.
98
Enantioselective Trifluoromethylalkynylation of Alkenes via Copper-Catalyzed Radical Relay.
Liang Fu, Song Zhou, Xiaolong Wan, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2018, 140, 10965–10969.
97
Copper-mediated intramolecular aminofluorination of 1,3-dienes by using nucleophilic fluorine reagents.
Zuxiao Zhang, Pinhong Chen,* Guosheng Liu* Chem. Commun. 2018, 54, 8709-8712.
96
Enantioselective Pd(II)-Catalyzed Intramolecular Oxidative 6-endo Aminoacetoxylation of Unactivated Alkenes.
46. Xiaoxu Qi,# Chaohuang Chen,# Chuanqi Hou, Liang Fu, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2018, 140, 7415?7419.
95
Decarboxylative Fluorination of Arylcarboxylic Acids Promoted by ortho-Hydroxy and Amino Groups.
Dinghai Wang, Zheliang Yuan, Qilun Liu, Pinhong Chen, Guosheng Liu* Chin. J. Chem. 2018, 36, 507-514.
94
Recent advances in hypervalent iodine(III)-catalyzed functionalization of alkenes.
Xiang Li, Pinhong Chen,* Guosheng Liu* Beilstein J. Org. Chem. 2018, 14, 1813–1825.
93
Divergent Synthesis of CF3-Substituted Allenyl Nitriles by Ligand-Controlled Radical 1,2- and 1,4-Addition to 1,3-Enynes.
Fei Wang, Dinghai Wang, Yu Zhou, Ling Liang, Ronghua Lu, Pinhong Chen, Zhenyang Lin,* Guosheng Liu* Angew. Chem. Int. Ed. 2018, 57, 7140 –7145.
92
Regioselective Palladium-Catalyzed C-H Bond Trifluoroethylation of Indoles: Exploration and Mechanistic Insight.
Hao Zhang, Hao-Yang Wang,* Yixin Luo, Chaohuang Chen, Yimiao Cao, Pinhong Chen, Yin-Long Guo, Yu Lan,* Guosheng Liu* ACS Catal. 2018, 8, 2173-2180.
91
Palladium-Catalyzed Intermolecular Ditrifluoromethoxylation of Unactivated Alkenes: CF3O?Palladation Initiated by Pd(IV).
Chaohuang Chen, Yixin Luo, Liang Fu, Pinhong Chen, Yu Lan,* Guosheng Liu* J. Am. Chem. Soc. 2018, 140, 1207?1210.

2017

90
Enantioselective Decarboxylative Cyanation Employing Cooperative Photoredox Catalysis and Copper Catalysis.
Dinghai Wang, Na Zhu, Pinhong Chen, Zhenyang Lin, Guosheng Liu* J. Am. Chem. Soc. 2017, 139, 15632?15635.
89
Palladium-Catalyzed Intermolecular Oxidative Diazidation of Alkenes.
Haihui Peng, Zheliang Yuan, Pinhong Chen, Guosheng Liu* Chin. J. Chem. 2017, 35, 876-880.
88
Recent Advances and Perspectives of Transition Metal-Catalyzed Asymmetric Fluorination Reactions.
Chaohuang Chen, Liang Fu, Pinhong Chen, Guosheng Liu* Chin. J. Chem. 2017, 35, 1781-1788.
87
Palladium-Catalyzed Intermolecular Azidocarbonylation of Alkenes via a Cooperative Strategy.
Ming Li,Feng Yu, Pinhong Chen, Guosheng Liu* J. Org. Chem. 2017, 82, 11682?11690.
86
Palladium-Catalyzed Intermolecular Oxidative Fluorocarbonylation of Unactivated Alkenes: Efficient Access of β-Fluorocarboxylic esters.
Xiaoxu Qi,Feng Yu, Pinhong Chen, Guosheng Liu* Angew. Chem. Int. Ed. 2017, 56, 12692-12696.
85
Catalytic Oxidative Trifluoromethoxylation of Allylic C-H Bonds using a Palladium Catalyst.
Xiaoxu Qi, Pinhong Chen, Guosheng Liu* Angew. Chem. Int. Ed. 2017, 56, 9517-9521.
84
Copper-Catalyzed Arylation of Benzylic C–H bonds with Alkylarenes as the Limiting Reagents.
Wen Zhang, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2017, 139, 7709-7712.
83
Asymmetric Copper-Catalyzed Intermolecular Aminoarylation of Styrenes: Efficient Access to Optical 2,2-Diarylethylamines.
Dinghai Wang, Lianqian Wu, Fei Wang, Xiaolong Wan, Pinhong Chen, Zhenyang Lin, Guosheng Liu* J. Am. Chem. Soc. 2017, 139, 6811-6814.
82
Enantioselective Palladium(II)-Catalyzed Intramolecular Aminoarylation of Alkenes by Dual N-H and Aryl C-H Bond Cleavage.
Wen Zhang, Pinhong Chen, Guosheng Liu* Angew. Chem. Int. Ed. 2017, 56, 5336-5340.
81
Setting Cyclohexane Stereochemistry with Oxidation
Fei Wang, Guosheng Liu* ACS Cent. Sci. 2017, 3, 161-162.
80
Asymmetric Cu-Catalyzed Intermolecular Trifluoromethylarylation of Styrenes: Enantioselective Arylation of Benzylic Radicals.
Lianqian Wu, Fei Wang, Xiaolong Wan, Dinghai Wang, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2017, 139, 2904-2907.
79
Enantioselective Copper-Catalyzed Intermolecular Amino- and Azidocyanation of Alkenes in a Radical Process.
Dinghai Wang, Fei Wang, Pinghong Chen, Zhenyang Lin,* Guosheng Liu* Angew. Chem. Int. Ed. 2017, 56, 2054-2058.

2016

78
Enantioselective Copper-Catalyzed Intermolecular Cyanotrifluoromethylation of Alkenes via Radical Process.
Fei Wang, Dinghai Wang, Xiaolong Wan, Lianqian Wu, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2016, 138, 15547-15550.
77
Author Profile of Guosheng Liu.
Guosheng Liu* Angew. Chem. Int. Ed. 2016, 55, 15206.
76
Palladium(II)-Catalyzed Oxidative Difunctionalization of Alkenes:Bond Forming at a High-Valent Palladium Center.
Guoyin Yin, Xin Mu, Guosheng Liu* Acc. Chem. Res. 2016, 49, 2413?2423.
75
Cooperative Strategy for the Highly Selective Intermolecular Oxycarbonylation Reaction of Alkenes using palladium catalyst.
Ming Li, Feng Yu, Xiaoxu Qi, Pinhong Chen, Guosheng Liu* Angew. Chem. Int. Ed. 2016, 55, 13843-13848.
74
Enantioselective cyanation of benzylic C–H bonds via copper-catalyzed radical relay.
  Wen Zhang,# Fei Wang,# Scott D. McCann, Dinghai Wang, Pinhong Chen, Shannon S. Stahl,* Guosheng Liu* Science 2016, 353, 1014-1018..
(# These author contributed equally to this work) Science 2016, 353, 1014-1018.
73
Efficient Pathway for the Preparation of Aryl(isoquinoline)iodonium(III) Salts and Synthesis of Radiofluorinated Isoquinolines.
Zheliang Yuan, Ran Cheng, Pinhong Chen, Guosheng Liu,* Steven Liang* Angew. Chem. Int. Ed. 2016, 55, 11882 –11886.
72
Mechanistic Investigation on the Silver-Catalyzed Oxidative Intramolecular Aminofluorination of Alkynes.
Tao Xu, Yichen Wu, Zheliang Yuan, Hairong Guan, Guosheng Liu* Organometallics 2016, 35, 1347-1349.
71
Pd(II)-Catalyzed Aminofluorination of Alkenes in Total Synthesis 6-(R)-Fluoroswainsonine and 5-(R)-Fluorofebrifugine.
Liang Wu, Pinhong Chen,* Guosheng Liu* Org. Lett. 2016, 18, 960-963.

2015

70
Palladium-Catalyzed Intramolecular Aminotrifluoromethoxylation of Alkenes.
Chaohuang Chen, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2015, 137, 15648-15651.
69
Copper-Catalyzed Trifluoromethylazidation of Alkynes: Efficient Access to CF3-Substituted Azirines and Aziridines.
Fei Wang, Na Zhu, Pinhong Chen, Jinxing Ye, Guosheng Liu* Angew. Chem. Int. Ed. 2015, 54, 9356-9360.
68
Abnormal Messianic Carbene Silver Complex: Synthesis, Reactivity, and Mechanistic Insight on Oxidative Fluorination
Qilun Liu, Zheliang Yuan, Hao-yang Wang,* Yang Li, Yicheng Wu, Tao Xu, Xuebing Leng, Pinhong Chen, Yin-long Guo, Zhenyang Lin,* Guosheng Liu* ACS Catal. 2015, 5, 6732–6737.
67
Palladium-Catalyzed Intermolecular Aminocarbonylation of Alkenes: Efficient Access of β-Amino Acid Derivatives.
Jiashun Cheng, Xiaoxu Qi, Ming Li, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2015, 137, 2480–2483.
66
Highly Selective Pd-Catalyzed Intermolecular Fluorosulfonylation of Styrenes.
Zheliang Yuan, Hao-Yang Wang, Xin Mu, Pinhong Chen, Yin-Long Guo, Guosheng Liu* J. Am. Chem. Soc. 2015, 137, 2468–2471.
65
Advances and challenges in palladium-catalyzed intermolecular selective allylic C-H functionalization of alkenes.
Xiaoxu Qi, Pinhong Chen, Guosheng Liu* Sci. China Chem. 2015, 58, 1249-1251.
64
Copper-Catalyzed Intermolecular Trifluoromethylazidation and Trifluoromethylthiocyanation of Allenes: Efficient Access to CF3-Containing Allyl Azides and Thiocyanates.
Na Zhu, Fei Wang, Pinhong Chen, Jinxing Ye,* Guosheng Liu* Org. Lett. 2015, 17, 3580-3583.
63
Palladium-Catalyzed Trifluoromethylthiolation of Arenes via C-H Activation.
Jiabin Xu, Pinhong Chen, Jingxing Ye,* Guosheng Liu* Acta Chim. Sinica 2015, 73, 1294-1297.
62
Pd(II)-catalyzed intermolecular enantioselective hydroamination of styrenes.
Feng Yu, Pinhong Chen,* Guosheng Liu* Org. Chem. Front. 2015, 2, 819-822.
61
Copper-Catalyzed Intermolecular Trifluoromethylthiocyanation of Alkenes: Convenient Access to CF3-Containing Alkyl Thiocyanates.
Zhaoli Liang, Fei Wang, Pinhong Chen, Guosheng Liu* Org. Lett. 2015, 17, 2438-2441.
60
Palladium-Catalyzed Intramolecular Aminoacetoxylation of Unactivated Alkenes with Hydrogen Peroxide as Oxidant.
Haitao Zhu, Pinhong Chen, Guosheng Liu** Org. Lett. 2015, 17, 1485-1488.
59
Advancements in Aminofluorination of Alkenes and Alkynes: Convenient Access to beta-Fluoroamines.
Pinhong Chen,* Guosheng Liu* Eur. J. Org. Chem. 2015, 4295-4309.
58
Pd-catalyzed intramolecular aminofluorination of allylic sulfamides.
Jiashun Cheng, Pinhong Chen, Guosheng Liu* Chin. J. Catal. 2015, 36, 40-47.

2014

57
Copper-Catalyzed Trifluoromethylthiolation of Aryl Halides with Diverse Directing Groups.
Jiabing Xu, Xin Mu, Pinhong Chen, Jinxing Ye*, Guosheng Liu* Org. Lett. 2014, 16, 3942-3945.
56
Branch-selective Allylic C-H Caboxylation of Terminal Alkenes by Pd/Sox Catalyst.
Hiroki Kondo, Feng Yu, Junichiro Yamaguchi, Guosheng Liu,* Kenichiro Itami,* Org. Lett. 2014, 16, 4212–4215.
55
Palladium-Catalyzed Cascade C-H Trifluoroethylation of Aryl Iodides and Heck Reaction: Efficient Synthesis of ortho-Trifluoroethylstyrenes.
Hao Zhang, Pinhong Chen, Guosheng Liu* Angew. Chem. Int. Ed. 2014, 53, 10174-10178.
54
Copper-Catalyzed Intermolecular Trifluoromethylarylation of Alkenes: Mutual Activation of Arylboronic Acid and CF3+ Reagent.
Fei Wang, Dinghai Wang, Xin Mu, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2014, 136, 10202-10205.
53
Copper-catalyzed Intermolecular Cyanotrifluoromethylation of Alkenes: Convenient Synthesis of CF3-containing Alkyl Nitriles.
Zhaoli Liang, Fei Wang, Pinhong Chen, Guosheng Liu* J. Fluorine Chem. 2014, 167, 55-60.
52
Copper-mediated/-catalyzed fluorination reactions: new routes to aryl fluorides.
Mu, Xin; Liu, Guosheng* Org. Chem. Front. 2014, 1, 430-433.
51
Copper-Catalyzed Intermolecular Trifluoromethylazidation of Alkenes: Convenient Access to CF3-Containing Alkyl Azides.
Wang, Fei; Qi, Xiaoxu; Liang, Zhaoli; Chen, Pinhong; Liu, Guosheng* Angew. Chem. Int. Ed. 2014, 53, 1881-1886.
50
Pd-Catalyzed Intramolecular Aminohydroxylation of Alkenes with Hydrogen Peroxide as Oxidant and Water as Nucleophile.
Zhu, Haitao; Chen, Pinhong; Liu, Guosheng* J J. Am. Chem. Soc. 2014, 136, 1766-1769.
49
Pallasium-catalyzed cascade cyclization for the construction of spiro-N,O-acetals.
Cheng, Jiashun; Chen, Pinhong; Liu, Guosheng* Org. Chem. Front. 2014, 1, 289-293.
48
Copper-catalyzed fluorination of 2-pyridyl aryl bromides.
Mu, Xin; Zhang, Hao; Chen, Pinhong; Liu, Guosheng* Chin. J. Chem. 2014, 32, 681-684.
47
AgF-Mediated Dialkylation of Activate Alkenes: An Efficient Access to Nitrile-Containing Spirooxindoles.
Liang Wu, Pinhong Chen, Guosheng Liu* Angew. Chem. Int. Ed. 2013, 52, 7549-7553.

2013

46
Copper-Catalyzed Regioselective Fluorination of Allylic Halides.
Zhang, Zuxiao;# Wang, Fei;# Mu, Xin; Chen, Pinhong; Liu, Guosheng* Angew. Chem. Int. Ed. 2013, 52, 7549-7553.
45
One-Pot Synthesis of 1-(Trifluoromethyl)4-fluoro-1,2-dihydroisoquinolines and 4,4-Difluoro-1,2,3,4-tetrahydro- isoquinolines.
Liu, Qilun; Wu, Yichen; Chen, Pinhong; Liu, Guosheng* Org. Lett. 2013, 15, 6210-6213.
44
Recent Advances in Transition-Metal-Catalyzed Trifluoromethylation and Related Transformations.
Chen, Pinhong; Liu, Guosheng* Synthesis 2013, 45, 2919-2939.
43
Palladium-Catalyzed Intermolecular Aminoacetoxylation of Alkenes and the Influence of Phl(OAc)2 on Aminopalladation Stereoselectivity.
Martinez, Claudio; Wu, Yichen; Weinstein, Adam B.; Stahl, Shannon S.;* Liu, Guosheng;* Mu?iz, Kilian* J. Org. Chem. 2013, 78, 6309–6315.
42
Regioselective palladium-catalyzed intramolecular oxidative aminofluorination of unactivated alkenes.
Wu, Tao; Cheng, Jiashun; Chen, Pinhong; Liu, Guosheng* Chem. Commun. 2013, 49, 8707-8709.
41
Palladium-catalyzed intermolecular fluoroesterification of styrenes: exploration and mechanistic insight.
Peng, Haihui; Yuan, Zheliang; Wang,Hao-yang; Guo, Yin-long; Liu, Guosheng * Chem. Sci. 2013, 4, 3172-3718.
40
Palladium-Catalyzed Intramolecular Fluorooxylation of Styrenes.
Yuan, Zheliang; Peng, Haihui; Liu, Guosheng* Chin. J. Chem. 2013, 31, 908-914.
39
Palladium-Catalyzed C-C Triple Bond Cleavage: Efficient Synthesis of 4H-Benzo[d][1,3]oxazin-4-ones.
Liu, Qilun; Chen, Pinhong; Liu, Guosheng* ACS Catal. 2013, 3, 178-181.

2012

38
Transition metal-catalyzed fluorination of multi carbon-carbon bonds: new strategies for fluorinated heterocycles.
Liu, Guosheng* Org. Biomol. Chem. 2012, 10, 6243-6248.
37
Ag(I)-Catalyzed Aminofluorination of Alkynes: Efficient Synthesis of 4-Fluoroisoquinolines and 4-Fluoropyrrolo[α]isoquinolines.
Xu, Tao; Liu, Guosheng* Org. Lett. 2012, 14, 5416-5419.
36
Palladium-Catalyzed Oxidative Arylalkylation of Unactivated Alkenes: Dual C-H Bond Cleavage of Anilines and Acetonitrile.
Zhang, Hao; Chen, Pinhong; Liu, Guosheng* Synlett 2012, 23, 1749-2752.
35
Palladium-Catalyzed Oxidative Aminofluorination of Styrenes.
Zhu Haitao; Liu Guosheng* Acta Chimica Sinica 2012, 70, 2404-2407.
34
Organocatalyzed arylalkylation of activated alkenes via decarboxylation of PhI(O2CR)2: efficient synthesis of oxindoles.
Wu, Tao; Zhang, Hao; Liu, Guosheng* Tetrahedron 2012, 68, 5229–5233.
33
Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature.
Mu, Xin; Wu, Tao; Wang, Hao-yang; Guo, Yin-long; Liu, Guosheng* J. Am. Chem. Soc. 2012, 134, 878-881.
32
Silver-Catalyzed Fluorination Reactions.
Xu, Tao; Liu, Guosheng* Synlett, 2012, 955-958.
31
Highly Selective Palladium-Catalyzed Intramolecular Chloroamination of Unactivated Alkenes by Using Hydrogen Peroxide as an Oxidant.
Yin, Guoyin; Wu, Tao; Liu, Guosheng* Chem. Eur. J. 2012, 18, 451-455.

2011

30
Palladium-Catalyzed Oxidative Arylalkylation of Activated Alkenes: Dual C-H Bond Cleavage of an Arene and Acetonitrile.
Wu, Tao; Mu, Xin; Liu, Guosheng* Angew. Chem. Int. Ed. 2011, 50, 12578-12581.
29
Silver-Catalyzed Intramolecular Aminofluorination of Activated Allenes.
Xu, Tao; Mu, Xin; Peng, Haihui; Liu, Guosheng* Angew. Chem. Int. Ed.2011, 50, 8176-8179.
28
Highly Selective Palladium-Catalyzed Intramolecular Aminonitroxylation of Alkenes.
Chen, Shujun; Wu, Tao; Liu, Guosheng;* Zhen, Xingliang SynLett, 2011, 891-894.
27
Palladium-Catalyzed Oxidative Trifluoromethylation of Indoles at Room Temperature.
Mu, Xin; Chen, Shujun; Zhen, Xingliang; Liu, Guosheng* Chem. Eur. J. 2011, 17, 6039-6042.
26
Palladium-Catalyzed Intramolecular Aminofluorination of Styrenes. (Invited Paper on the occasion of Prof. Weiyuan Huang’s 90th birthday)
Xu, Tao; Qiu, Shuifa; Liu, Guosheng* Chin. J. Chem. 2011, 29, 2785-2790.
25
Palladium-Catalyzed Tandem Fluorination and Cyclization of Enynes.
Peng, Haihui; Liu, Guosheng* Org. Lett. 2011, 13, 772-775.
24
Organocatalyzed cycloaddition of carbon dioxide to aziridines.
Wu, Yichen; Liu, Guosheng* Tetrahedron Lett. 2011, 52, 6450-6452.
23
Mechanistic Studies of Wacker-Type Intramolecular Aerobic Oxidative Amination of Alkenes Catalyzed by Pd(OAc)2/Pyridine.
Ye, Xuan; Liu, Guosheng; Popp, Brian V.; Stahl Shannon S.** J. Org. Chem. 2011, 76, 1031–1044.
22
Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications.
McDonald, Richard I.; Liu, Guosheng; Stahl, Shannon S.* Chem. Rev., 2011, 111, 2981–3019.
21
Palladium-catalyzed inter- and intramolecular hydroamination of styrenes coupled with alcohol oxidation using N-fluorobenzenesulfonimide as the oxidant
Xu, Tao; Qiu, Shuifa; Liu, Guosheng* J. Organomet. Chem. 2011, 696, 46-49.

2010

20
Palladium-Catalyzed Allylic C–H Bond Functionalization of Olefins.
Liu, Guosheng;* Wu Yichen C-H Activation: Topics in Current Chemistry, 2010, 292, 195-209.
19
Palladium-Catalyzed Intermolecular Aminofluorination of Styrenes.
Qiu, Shuifa; Xu, Tao; Zhou, Juan; Guo, Yinlong; Liu, Guosheng* J. Am. Chem. Soc. 2010, 132, 2856–2857.
18
Scope and Mechanism of Allylic C?H Amination of Terminal Alkenes by the Palladium/PhI(OPiv)2 Catalyst System: Insights into the Effect of Naphthoquinone.
Yin, Guoyin; Wu, Yichen; Liu, Guosheng* J. Am. Chem. Soc. 2010, 132, 11978-11987.

2009

17
Palladium-Catalyzed Intramolecular Aminofluorination of Unactivated Alkenes.
Wu, Tao; Yin, Guoyin; Liu, Guosheng* J. Am. Chem. Soc. 2009, 131, 16354-16355.
16
 Palladium-Catalyzed Intramolecular Hydro- amination of Allenes Coupled to Aerobic Alcohol Oxidation. 
127. Shuifa Qiu, Yunyang Wei, Guosheng Liu* Chem. Eur. J. 2009, 15, 2751-2754.
15
Palladium-Catalyzed Intramolecular Hydro- amination of Allenes Coupled to Aerobic Alcohol Oxidation.
Wu, Liang; Qiu, Shuifa; Liu, Guosheng* Org. Lett. 2009, 11, 2707-2710.

2008

14
Palladium-catalyzed intermolecular aerobic oxidative amination of terminal alkenes: efficient synthesis of linear allylamine derivatives.
Liu, Guosheng;* Yin, Guoyin; Wu, Liang Angew. Chem. Int. Ed. 2008, 47, 4733-4736.
13
Palladium-catalyzed oxidative cyclization of enyne with hydrogen peroxide as the oxidant.
Yin, Guoyin; Liu, Guosheng* Angew. Chem. Int. Ed. 2008, 47, 5442-5445.

Before 2008

12
Cobalt-Catalyzed Carbonylative Polymerization of Azetidines.
Chai, Jianfang; Liu, Guosheng; Chaicharoen, Kittisak; Wesdemiotis, Chrys; Jia, Li* Macromolecules 2008, 41, 8980-8985.
11
Two-Faced Reactivity of Alkenes: cis- versus trans-aminopalladation in Aerobic Pd-Catalyzed Intramolecular Aza-Wacker Reactions.
Liu, Guosheng; Stahl, Shannon. S.* J. Am. Chem. Soc. 2007, 129, 6328-6335.
10
Highly Regeioselective Pd-Catalyzed Intermolecular Aminoacetoxylation of Alkene and Evidence for the cis-Aminopalladation and SN2 C-O Bond Formation.
Liu, Guosheng; Stahl, Shannon. S.* J. Am. Chem. Soc. 2006, 128, 7179-7181.
09
Cobalt-Catalyzed Carbonylative Copolymerizaiton of N-Alkylazetidines and Tetrahydrofuran.
Liu, Guosheng; Jia, Li* Angew. Chem. Int. Ed. 2005, 45, 129-131.
08
Design of Catalytic Carbonylative Polymerizations of Heterocylces. Synthesis of Polyesters and Amphiphilic Poly(amide-block-ester)s.
Liu, Guosheng; Jia, Li* J. Am. Chem. Soc. 2004, 126, 14716-14717.
07
A novel highly regio- and diastereoselective haloamination of alkenes catalyzed by divalent palladium.
Lei, Aiwen; Liu, Guosheng; Lu, Xiyan* Tetrahedron Lett. 2004, 45, 1785-1788.
06
One-pot synthesis of tetrahydrofuran derivatives via a divalent palladium-catalyzed three-component coupling.
Liu, Guosheng; Lu, Xiyan* Tetrahedron Lett. 2003, 44, 467-470.
05
Palladium(II)-Catalyzed Coupling of Allenoic Acids and a,b-Unsaturated Carbonyl Compounds through Tandem Intramolecular oxypalladation and Conjugate Addition Reactions
Liu, Guosheng; Lu, Xiyan* Tetrahedron Lett. 2003, 44, 127-130.
04
Palladium(II)-Catalyzed Highly Regio- and Diastereoselective Cyclization of Difunctional Allylic N-Tosylcarbamates. A Convenient Synthesis of Optically Active 4-Vinyl-2-oxazolidinones and Total Synthesis of 1,4-Dideoxy-1,4-imino- L-xylitol.
Lei, Aiwen; Liu, Guosheng; Lu, Xiyan* J. Org. Chem. 2002, 67, 974-980.
03
Palladium(II)-Catalyzed Coupling Reactions of Intramolecular Carbopalladation of Alkyne with Allylic Compounds.
Liu, Guosheng; Lu, Xiyan* Tetrahedron Lett. 2002, 43, 6791-6794.
02
Palladium(II)-Catalyzed Tandem Reaction of Intramolecular Aminopalladation of Allenyl N-Tosylcarbamates and Conjugate Addition.
Liu, Guosheng; Lu, Xiyan* Org. Lett. 2001, 3, 3879-3882.
01
Asymmetric cyclopropanation of styrene catalyzed by Cu-(chiral Schiff-base) complexes.
Li, Zhengning;* Liu, Guosheng; Zheng, Zhuo; Chen, Huilin Tetrahedron 2000, 56, 7187-7191.

Book Charpter

14
Liu, Guosheng, Ed. Science of Synthesis KnowledgeUpdates: Volume 47: Alkenes, Thieme: New York, 2023
13
Chen, Pinhong; Liu, Guosheng,* “Radical Addition Reactions”, In Science of Synthesis: Volume 47:  Alkenes (G. Liu, Ed), Thieme: New York, 2023.
12
Chen, Pinhong; Liu, Guosheng,* “Copper-Catalyzed C-H Functionalization via Radicals”, in Science of Synthesis Reference Library: Base-Metal Catalysis, (N. Yoshkai, Ed), Thieme: New York, 2022.
11
Chen, Pinhong; Liu, Guosheng,* Bifunctionalization-Based Catalytic Fluorination and Trifluoromethylation, in Organofluorine Chemistry: Synthesis, Modeling, and Applications, (Szabo, K. J.; Selander, N., Eds), WILEY-VCH GmbH, Boschstr. 2022.
10
Chen, Chaohuang.; Liu, Guosheng,* “Direct Trifluoromethoxylation of Aliphatic Compounds”, in Emerging Fluorinated Motifs: Synthesis, Properties, and Applications, Volume 2 (D. Cahard, J.-A. Ma, Eds), Wiley‐VCH Verlag GmbH & Co. KGaA. 2020.
09
Chen, Chaohuang.; Chen, Pinhong; Liu, Guosheng,* “N,N’-Difluoro-1,4-Diazoniabicyclo[2.2.2]-octane Salt Electrophilic Fluorination", in Synthetic Organofluorine Chemistry: Fluorination (J. Hu,; T. Umemoto, Eds,), Springer, 2020.
08
Liu, Guosheng,* “Fluorination of Alkenes and Alkynes for Preparing Alkyl Fluorides”, in Synthetic Organofluorine Chemistry: Fluorination (J. Hu,; T. Umemoto, Eds,), Springer, 2020.
07
Chen, Pinhong; Liu, Guosheng,* “Allylic, Benzylic, and Propargylic Oxidation” in Science of Synthesis: Catalytic Oxidation in Organic Synthesis (K. Müniz, Ed), Thieme: New York, 2017.
06
Liu, Guosheng;* Chen, Pinhong; “C-C and C-X Bond Formation by Allylic C-H Activation” in Reference Library: Catalytic Transformations via C—H Activation 2, Workbench Edition (Jin-Quan Yu, Ed.), Thieme: New York, 2016.

05

Chen,Pinhong; Liu, Guosheng;*  Engle, Keary M.;Yu, Jin-Quan;* “High-Valent Palladium in Catalysis”,in Houben-Weyl: Science of Synthesis knowledge Updates,volume 1: Compounds with Transition-Metal-Carbon p-Bond and Compounds of Group 10-8 (Ni,Pt,Co,Rh,Ir,Fe,Os),(B. M. Trost,P. J. Plietker,Eds.),Thieme: New York,2013.
04
Mu, Xin; Liu, Guosheng;* “Chapter 11,Dioxygen-Coupled Palladium and Copper-Catalyzed Csp2-H Functionalization: Reactions and Mechanisms” in C-H and C-X Bond Functionalization: Transition Metal Mediation (X. Ribas,Ed.) RSC Publishing,2013.
03
Liu, Guosheng;* Wu, Yichen “Bathocupronie”, in e-EROS Encyclopedia of Reagents for Organic Synthesis (D. Crich, P. L. Fuchs, A. B. Charette, T Rovis, Eds.), Wiley-Interscience, 2011.

02

刘国生 (Liu Guosheng), “金属催化的合成反应”, 高速发展的中国化学1982-2012, 科学出版社, 2012年.

01

刘国生 (Liu Guosheng), “绿色氧化”, 10000 个科学难题-化学卷, 267-269页, “10000 个科学难题”化学编委会主编, 科学出版社, 2009 年.